Silica supported palladium-phosphine complex: recyclable catalyst for Suzuki-Miyaura cross-coupling reactions at ambient temperature

被引:61
|
作者
Chen, Wei [1 ]
Li, Pinhua [1 ]
Wang, Lei [1 ,2 ]
机构
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
基金
中国国家自然科学基金;
关键词
Immobilized catalyst; Palladium-phosphine complex; Suzuki-Miyaura reactions; Recyclability; ASYMMETRIC MICHAEL ADDITION; INORGANIC HYBRID MATERIALS; HIGHLY-ACTIVE CATALYST; ALDEHYDE-ALKYNE-AMINE; IONIC LIQUID; DIHYDROFOLATE-REDUCTASE; PNEUMOCYSTIS-CARINII; REUSABLE CATALYST; IMMOBILIZED PYRROLIDINE; OLEFIN METATHESIS;
D O I
10.1016/j.tet.2010.11.042
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new silica immobilized palladium-phosphine complex has been developed. It was found to be an efficient catalyst for Suzuki-Miyaura cross-coupling reactions under mild conditions. It is important to note that the supported catalyst could be reused at least 10 times without a significant loss of catalytic activity. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:318 / 325
页数:8
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