Efficient and Selective Room-Temperature Gold-Catalyzed Reduction of Nitro Compounds with CO and H2O as the Hydrogen Source

被引：210
|
作者：
He, Lin [1 ]
Wang, Lu-Cun [1 ]
Sun, Hao [1 ]
Ni, Ji [1 ]
Cao, Yong [1 ]
He, He-Yong [1 ]
Ean, Kang-Nian [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期
关键词：
chemoselectivity; gold; nitro compounds; reduction; sustainable chemistry; AEROBIC ALCOHOL OXIDATION; OXIDE-SUPPORTED GOLD; GAS SHIFT REACTION; AROMATIC-AMINES; CHEMOSELECTIVE HYDROGENATION; CO/H2O CONDITIONS; ACTIVE-SITES; WATER; NANOPARTICLES; SIZE;
D O I：
10.1002/anie.200904647
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Chemical equation presented] Taking hydrogen from water: Gold catalysis enabled the selective reduction of nitro compounds under very mild conditions with a combination of H2O and CO as the reductant (see scheme). This environmentally friendly reaction proceeded in high yield and with high chemoselectivity in the presence of a wide range of functional groups © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
引用
收藏
页码：9538 / 9541
页数：4
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