The effect of Ca, Ba, and V2O5 on oxide-film stability and the mechanism of oxidation of disperse aluminum

被引:3
|
作者
Shevchenko, V. G. [1 ]
Krasil'nikov, V. N. [1 ]
Eselevich, D. A. [1 ]
Konyukova, A. V. [1 ]
机构
[1] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620990, Russia
基金
俄罗斯基础研究基金会;
关键词
aluminum powders; oxidation; modification; mechanism of action; KINETICS; POWDERS; SURFACE; CALCIUM; BARIUM;
D O I
10.1134/S2070205117050215
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The results of a reactivity study of aluminum powders modified with surfactants of different natures allowing one to decrease the protective properties of an oxide film on a particle surface during heating in the oxidizing medium are given. Ca, Ba, and V2O5 used as modifiers were shown to allow considerably increasing the completeness and rate of oxidation of ASD-4-type aluminum powders used as fuels in composite propellant compositions. The mechanism of action of modifiers on the oxidation and combustion of disperse aluminum was established.
引用
收藏
页码:835 / 840
页数:6
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