Electrostatically Self-Assembled Nanocomposite Reactive Microspheres

被引:77
|
作者
Malchi, Jonathan Y. [1 ]
Foley, Timothy J. [2 ]
Yetter, Richard A. [1 ]
机构
[1] Penn State Univ, University Pk, PA 16802 USA
[2] Los Alamos Natl Lab, Los Alamos, NM USA
关键词
electrostatic self-assembly; nanoenergetics; thermites; microspheres; BINARY NANOPARTICLE SUPERLATTICES; ORGANIZED MOLECULAR ASSEMBLIES; OXIDIZED ALUMINUM SURFACE; NORMAL-ALKANOIC ACIDS; MONOLAYERS; ALKANETHIOLS; CRYSTALS; AL/MOO3; AU;
D O I
10.1021/am900521w
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nanocomposite reactive microspheres with diameters of similar to 1-5 mu m were created via electrostatic self-assembly of aluminum and cupric oxide nanoparticles. The ability to utilize this novel approach of bottom-up assembly to create these reactive materials allows for the potential for a more intimate mixture between the two nanoreactants and, thus, an overall more energetic combustion process. Experiments with the self-assembled material demonstrate the ability to achieve ignition and sustain a combustion wave in rectangular microchannels, which does not occur with material having similar amounts of organics mixed via the traditional sonication method.
引用
收藏
页码:2420 / 2423
页数:4
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