Electrostatically Self-Assembled Nanocomposite Reactive Microspheres

被引:77
|
作者
Malchi, Jonathan Y. [1 ]
Foley, Timothy J. [2 ]
Yetter, Richard A. [1 ]
机构
[1] Penn State Univ, University Pk, PA 16802 USA
[2] Los Alamos Natl Lab, Los Alamos, NM USA
关键词
electrostatic self-assembly; nanoenergetics; thermites; microspheres; BINARY NANOPARTICLE SUPERLATTICES; ORGANIZED MOLECULAR ASSEMBLIES; OXIDIZED ALUMINUM SURFACE; NORMAL-ALKANOIC ACIDS; MONOLAYERS; ALKANETHIOLS; CRYSTALS; AL/MOO3; AU;
D O I
10.1021/am900521w
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nanocomposite reactive microspheres with diameters of similar to 1-5 mu m were created via electrostatic self-assembly of aluminum and cupric oxide nanoparticles. The ability to utilize this novel approach of bottom-up assembly to create these reactive materials allows for the potential for a more intimate mixture between the two nanoreactants and, thus, an overall more energetic combustion process. Experiments with the self-assembled material demonstrate the ability to achieve ignition and sustain a combustion wave in rectangular microchannels, which does not occur with material having similar amounts of organics mixed via the traditional sonication method.
引用
收藏
页码:2420 / 2423
页数:4
相关论文
共 50 条
  • [1] Characterization of electrostatically self-assembled nanocomposite thin films
    Liu, Yanjing
    Rosidian, Aprillya
    Lenahan, Kristie
    Wang, You-Xiong
    Zeng, Tingying
    Claus, Richard O.
    Smart Materials and Structures, 1999, 8 (01): : 100 - 105
  • [2] Characterization of electrostatically self-assembled nanocomposite thin films
    Liu, YJ
    Rosidian, A
    Lenahan, K
    Wang, YX
    Zeng, TY
    Claus, RO
    SMART MATERIALS & STRUCTURES, 1999, 8 (01): : 100 - 105
  • [3] Phase Diagrams of Electrostatically Self-Assembled Amphiplexes
    Stanic, Vesna
    Mancuso, Matthew
    Wong, Waiken
    DiMasi, Elaine
    Strey, Helmut H.
    MACROMOLECULES, 2011, 44 (18) : 7423 - 7429
  • [4] Raman Characterization of Oligoaniline Self-Assembled Microspheres
    Ferreira, Daniela C.
    Temperini, Marcia L. A.
    XXII INTERNATIONAL CONFERENCE ON RAMAN SPECTROSCOPY, 2010, 1267 : 689 - 690
  • [5] ZnO microspheres self-assembled by hexagonal nanoplates
    Wang, HH
    Xie, CS
    Zeng, DW
    CHEMISTRY LETTERS, 2005, 34 (02) : 260 - 261
  • [6] Fabrication of microspheres from self-assembled γ-peptides
    Maity, Suman Kumar
    Bera, Santu
    Paikar, Arpita
    Pramanik, Apurba
    Haldar, Debasish
    CRYSTENGCOMM, 2013, 15 (29): : 5860 - 5866
  • [7] Regent progress in electrostatically self-assembled thin films.
    Claus, RO
    Liu, YJ
    Cooper, KL
    Zeng, TY
    Zhang, FJ
    Jiang, LP
    Chen, YS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U576 - U576
  • [8] Electrostatically self-assembled electro-optic materials and devices
    Cooper, KL
    Zhang, L
    Zeng, T
    Claus, RO
    SMART STRUCTURES AND MATERIALS 2001: ACTIVE MATERIALS: BEHAVIOR AND MECHANICS, 2001, 4333 : 104 - 110
  • [9] Photoswitched Protein Adsorption on Electrostatically Self-Assembled Azobenzene Films
    Zhang, Jian
    Hu, Te
    Liu, Yibiao
    Ma, Yanxuan
    Dong, Jie
    Xu, Liping
    Zheng, Yudong
    Yang, Huai
    Wang, Guojie
    CHEMPHYSCHEM, 2012, 13 (11) : 2671 - 2675
  • [10] Electrostatically self-assembled electro-optic thin films
    Cooper, KL
    Liu, Y
    Claus, RO
    Zhang, L
    PHOTONIC DEVICES AND ALGORITHMS FOR COMPUTING II, 2000, 4114 : 88 - 94