Approximate Expressions for the One-Temperature Non-Equilibrium Reaction Rates

被引:3
|
作者
Gorbachev, Yuriy E. [1 ]
机构
[1] Coddan Technol LLC, Res Dept, St Petersburg 197342, Russia
关键词
Physical-chemical gas-dynamics; kinetic theory; Boltzmann equation; reactive mixture; transport equations; non-equilibrium reaction rates; GAS-DYNAMIC EQUATIONS; INTERNAL DEGREES; MIXTURES;
D O I
10.1063/1.5044156
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
Approximate expressions for the spatially homogeneous and spatially in homogeneous corrections to the equilibrium reaction rates obtained within the renormalization technique developed in the previous papers have been derived. Arbitral set of the chemical reactions is considered. Obtained reaction rates depend on the heat capacities of the species participation in the chemical reactions. This reflects the quasi-stationary process of the exchange of the energy between the translational and internal degrees of freedom of the reacting species.
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页数:4
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