Progress report

被引:11
|
作者
Lappert, MF [1 ]
机构
[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England
基金
英国工程与自然科学研究理事会;
关键词
ligand design; MX2; (M; Si; Ge; Sn; Pb); 1-azaallyl; beta-diketiminates; amides; lanthanides;
D O I
10.1016/S0022-328X(00)00061-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This paper provides a brief resume of our current researches in organometallic chemistry. The first deals with non-classical organolanthanoid chemistry, which has, as targets, subvalent compounds of the early 4f elements (La, Ce, Pr, Nd) and cationic organosamarium(II) and -ytterbium(II) complexes. The second is concerned with new aspects of metal amide chemistry including (a) silver(I) amides and isonitrile complexes of lithium amides: (b) derivatives of aromatic diamides such di(metalamino)cyclophanes; (c) metal silyl complexes derived from insertion of a stable silylene into M(II)-N(SiMe3)(2) (M = Ge, Sn or Pb) bonds: and (d) reactions of M'-X compounds with 1,3,5-triazine [M' = Li or Na and X = N(SiMe3)(2), C(SiMe3)(3) or CH(SiMe3)(2)] The two other present areas ton subvalent compounds of Group 14 elements and metal 1-azaallyls, beta-diketiminates and 1,3-diazaallyls) are reported more cursorily. The Introduction is divided into three sections entitled 'Relationship to the Journal of Organometallic Chemistry', 'Reviews (from 1956 to 1995)' and 'An outline of principal contributions'. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:144 / 158
页数:15
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