Cis,cis,cis-(acetato-O,O′)bis[1,2-bis(diphenylphosphino)ethane-P,P′]ruthenium(II) hexafluorophosphate dimethanol solvate

被引：7
|
作者：
Lucas, NT [1 ]
Powell, CE [1 ]
Humphrey, MG [1 ]
机构：
[1] Australian Natl Univ, Dept Chem, Canberra, ACT 0200, Australia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷
关键词：
D O I：
10.1107/S0108270100011082
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the cation of the title complex, cis,cis,cis-[Ru(eta(2)O(2)CMe)(dppe)(2)]PF6. 2MeOH [dppe is 1,2-bis(diphenylphosphino)ethane, C26H24P2], the Ru atom is in a pseudooctahedral coordination environment with two chelating dppe ligands and one chelating acetate ligand. Intra-phosphine and intra-acetate bond lengths and angles are unexceptional. Deviations from idealized octahedral coordination angles at ruthenium [O-Ru-O 59.43 (8)degrees and P-Ru-P 103.19 (2)degrees] presumably derive from constraints imposed by the chelate rings. The Ru-P distances for the mutually trans P-donor atoms [2.3785 (6) Angstrom] are significantly longer than those for the Ru-P linkages trans to the acetate ligand [2.3074 (6) Angstrom]. The Ru1, C1 and C2 atoms lie on a twofold axis, and atom P3 of the anion lies on an inversion centre.
引用
收藏
页码：E392 / E393
页数：2
相关论文
共 50 条
  • [21] Trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane-κ2 P, P′](phenylethynyl)ruthenium(II) hexafluorophosphate ethanol hemisolvate
    Willis, Anthony C.
    Powell, Clem E.
    Humphrey, Mark G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2473 - M2475
  • [22] Investigation of {1,2-bis(diphenylphosphino)ethane-P,P'}-(dithiocarbonato-S,S')-nickel(II)
    Travnicek, Z
    Pastorek, R
    Sindelar, Z
    Klicka, R
    Marek, J
    TRANSITION METAL CHEMISTRY, 1996, 21 (01) : 81 - 84
  • [23] CONVENIENT SYNTHESIS OF CIS-1,2-BIS(DIPHENYLPHOSPHINO)-ETHANE-PLATINUM(II)-ACETYLIDES
    SEBALD, A
    WRACKMEYER, B
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1983, 38 (09): : 1156 - 1158
  • [24] BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]-PLATINUM(II) IODIDE BIS(DEUTERIOCHLOROFORM) SOLVATE
    FERGUSON, G
    LOUGH, AJ
    MCALEES, AJ
    MCCRINDLE, R
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 573 - 576
  • [25] [1,2-bis(diphenylphosphino)ethane]dibromonickel(II) tetrahydrofuran solvate
    Beaudoin, S
    Zargarian, D
    Bélanger-Gariépy, F
    Fontaine, FG
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : m433 - m434
  • [26] CIS-DICHLORO[1,2-BIS(DICYCLOHEXYLPHOSPHINO)-ETHANE]PALLADIUM(II)
    GANGULY, S
    MAGUE, JT
    ROUNDHILL, DM
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 217 - 219
  • [27] cis-[1,2-Bis(diphenylarsanyl)ethane-κ2As,As′]tetracarbonylchromium(0)
    Norlidah, M. N.
    Azhar, M. Y.
    Bin Shawkataly, Omar
    Rosli, Mohd Mustaqim
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1267 - U1011
  • [28] CHARACTERIZATION OF BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]RHODIUM(O)
    NANNI, E
    KUNIN, A
    EISENBERG, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 184 (SEP): : 148 - INOR
  • [29] cis-Aquabis[bis(diphenylphosphino)ethane-κ2P,P′]-chlororuthenium(II) hexafluorophosphate dichloromethane sesquisolvate hemihydrate
    Russo, L
    Figueira, J
    Rodrigues, J
    Rissanen, K
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M699 - M701
  • [30] A STRUCTURAL STUDY ON BIS(TRANS-[BIS(DIPHENYLPHOSPHINO)ETHYLENE])-TRICARBONYLIRON(O) AND CIS-[BIS(DIPHENYLPHOSPHINO)ETHYLENE]-TRICARBONYLIRON(O)
    LUH, LS
    LIU, LK
    INORGANICA CHIMICA ACTA, 1993, 206 (01) : 89 - 95
12345