Nanoheterogeneous Multilayer Films with Perfluorinated Domains Fabricated Using the Layer-by-Layer Method

被引：11
|
作者：
Niemiec, Wiktor [1 ]
Zapotoczny, Szczepan [1 ]
Szczubialka, Krzysztof [1 ]
Laschewsky, Andre [2 ]
Nowakowska, Maria [1 ]
机构：
[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
[2] Fraunhofer Inst Angew Polymerforsch FhG IAP, D-14476 Potsdam, Germany
来源：
LANGMUIR | 2010年 / 26卷 / 14期
关键词：
ORDERED POLYELECTROLYTE MULTILAYERS; FREE-RADICAL POLYMERIZATION; SELF-ASSEMBLY PROCESS; CHARGED SURFACES; ULTRATHIN FILMS; THIN-FILMS; BUILDUP; TEMPERATURE; ADSORPTION; COPOLYMERS;
D O I：
10.1021/la1012044
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nanoheterogenous ultrathin films containing perfluorinated domains were prepared via the layer-by-layer (LbL) electrostatic self-assembly method. The films are constructed from the amphiphilic cationic copolymer with perfluorinated side chains and poly(sodium styrenesulfonate) (PSS). The LbL process was optimized by the application of sonication which allowed linear growth of the him. The resulting film exhibited micellar structure with isolated fluorocarbon hydrophobic domains. The remarkable features of the films were their switchable wettability and friction properties. The obtained water-processable films can find a number of potential applications, e.g., as smart and low friction coatings.
引用
收藏
页码：11915 / 11920
页数：6
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