Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable Hydrogen Donor

被引：28
|
作者：
Saito, Kodai [1 ]
Miyashita, Hiromitsu [1 ]
Akiyama, Takahiko [1 ]
机构：
[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 20期
基金：
日本学术振兴会;
关键词：
CATALYZED TRANSFER HYDROGENATION; ORGANOCATALYTIC TRANSFER HYDROGENATION; BRONSTED ACID CATALYST; HANTZSCH ESTERS; KINETIC RESOLUTION; NAD(P)H MODEL; NADH MODELS; METAL-FREE; REDUCTION; BENZOTHIAZOLINE;
D O I：
10.1021/ol502486f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The chiral phosphoric acid catalyzed enantioselective transfer hydrogenation of various ketimines was achieved by the use of 2-aryl indoline as the hydrogen donor. Corresponding chiral amines were obtained in good chemical yields with excellent enantioselectivities.
引用
收藏
页码：5312 / 5315
页数：4
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