Reductive CO2 Fixation via Tandem C-C and C-N Bond Formation: Synthesis of Spiro-indolepyrrolidines

被引：63

作者：

Zhu, Dao-Yong ^{[1
]}

Fang, Lei ^{[1
]}

Han, Hui ^{[1
]}

Wang, Yazhou ^{[1
]}

Xia, Ji-Bao ^{[1
]}

机构：

[1] Chinese Acad Sci, LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 16期

关键词：

CARBON-DIOXIDE; HETEROCYCLIC CARBENE; CATALYTIC METHYLATION; BUILDING-BLOCK; METAL-FREE; H BONDS; ENANTIOSELECTIVE CONSTRUCTION; CARBOXYLIC-ACIDS; UNIFIED STRATEGY; AMINES;

D O I：

10.1021/acs.orglett.7b01906

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe herein a tendem C-C and C-N bond forming reaction in the reductive functionalization of CO2, an abundant and cheap Cl chemical-feedstock. This catalytic Metal-free CO2, fixation afforded spiro-indoleyrrolidines by dearomatization of tryptamine derivatives with broad scope and good functional group tolerance under mild conditions.

引用

页码：4259 / 4262

页数：4

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