Synthesis and Crystal Structure of 4,4′Di-2-pyridy1-2,2′-dithiodipyrimidine (C18H12N6S2)

被引：0
|
作者：
Dong, Hua-Ze [1 ]
Zhu, Hai-Bin [2 ]
机构：
[1] Hefei Normal Univ, Dept Chem & Chem Engn, Hefei 230061, Peoples R China
[2] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2010年 / 22卷 / 06期
关键词：
4-Pyridin-2-yl-pyrintidine-2-thiol; Hydrogen bonds; Heterocylic sulfide;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new heterocylic sulfide ligand with molecular formula C18H12N6S2, named as 4,4'-di-2-pyridy1-2,2'-dithiodipyrimidine, was formed by the reaction of 4-pyridin-2-yl-pyrimidine-2-thiol with ferric nitrate. The crystal is monoclinic, space group P2(1)/c with unit cell parameters: a = 11.777 (2) angstrom, b = 7.2830 (15) angstrom. c = 20.182 (4) angstrom, alpha = 90 degrees, beta = 98.832 (4)degrees, gamma = 90 degrees, V = 1710.5 (6) angstrom(3), Z = 4,-MT = 376.47, Dc= 1.470 g/cm(3), mu = 0.327 mm(-1), F(000) = 776, R = 0.0378, wR = 0.0749 for 1820 reflections with I > 2 sigma(1).
引用
收藏
页码：4956 / 4958
页数：3
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