Dioxouranium complexes of 2,2′-dihydroxyazobenzene:: Binding of mono- and bidentate Lewis bases

被引:0
|
作者
Nag, JK [1 ]
Chattopadhyay, P [1 ]
Misra, TK [1 ]
Sinha, C [1 ]
机构
[1] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uranyl complexes of 2,2'-dihydroxyazobenzene (H2L) and its adducts with monodentate (B) and bidentate (B-B) Lewis bases of the type [UO2L.B.H2O] (B = py, gamma-pic, imz, dmf, dmso, tppo) and [UO2L(B-B)](B-B = bpy, ophen, dpa) are described. The complexes are pentagonal bipyramidal. The five coordination positions on the equator are occupied by the combination of ligand L-=, B, H2O or B-B.
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页码:270 / 272
页数:3
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