The Ubbelohde effect in hydrogen-bonded crystalline K3H(SO4)2

被引:16
|
作者
Sugimoto, H [1 ]
机构
[1] Chuo Univ, Fac Sci & Engn, Dept Phys, Bunkyo Ku, Tokyo 112, Japan
关键词
D O I
10.1088/0953-8984/10/6/007
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We present a new model reproducing the temperature dependence of hydrogen-bond lengths observed in K3H(SO4)(2) (KHS) and K3D(SO4)(2) (DKHS). The model also gives a consistent account of the Ubbelohde effect and the disappearance of an ordered phase in KHS.
引用
收藏
页码:1237 / 1246
页数:10
相关论文
共 50 条
  • [41] Production of Complex Hydrosulphates in the K3H(SO4)2–Rb3H(SO4)2 Series: II. Phase Equilibria in the K2SO4–Rb2SO4–H2SO4–H2O System
    I. S. Timakov
    V. V. Grebenev
    V. A. Komornikov
    O. B. Zainullin
    I. P. Makarova
    E. V. Selezneva
    I. I. Kuzmin
    Crystallography Reports, 2022, 67 : 455 - 463
  • [42] EPR study of VO2+ center in fast proton conductor K3H(SO4)2
    Ostrowski, A
    Waplak, S
    Bednarski, W
    ACTA PHYSICA POLONICA A, 2005, 108 (01) : 127 - 135
  • [43] EPR Study of Cr3+ Center in Fast-Proton Conductor K3H(SO4)2
    A. Ostrowski
    S. Waplak
    Applied Magnetic Resonance, 2008, 34 : 55 - 61
  • [44] EPR study of Cr3+ center in fast-proton conductor K3H(SO4)2
    Ostrowski, A.
    Waplak, S.
    APPLIED MAGNETIC RESONANCE, 2008, 34 (1-2) : 55 - 61
  • [45] Pseudospin Hamiltonian parameters from quantum chemical treatment:: K3H(SO4)2 (TKHS) family
    Dolin, SP
    Levin, AA
    Mikhailova, TY
    Strokach, NS
    Kirillova, NI
    FERROELECTRICS, 2003, 283 : 115 - 125
  • [46] High temperature phase transition and multiphase state formation in K3H(SO4)2 superprotonic conductor
    Ostrowski, A.
    Bednarski, W.
    SOLID STATE IONICS, 2017, 301 : 152 - 155
  • [47] Quantum-chemical approach to zerodimensional antiferroelectrics and quantum paraelectrics of the K3H(SO4)2 family
    Dolin, SP
    Levin, AA
    Mikhailova, TY
    Solin, MV
    VIBRONIC INTERACTIONS: JAHN-TELLER EFFECT IN CRYSTALS AND MOLECULES, 2001, 39 : 263 - 268
  • [48] Crystal-field-fluctuation in fast proton conductor K3H(SO4)2 studied by EPR
    Waplak, S
    Bednarski, W
    18TH CONFERENCE ON RADIO- AND MICROWAVE SPECTROSCOPY, RAMIS'99, 2000, 28 : 122 - 125
  • [49] Structural phase transition, ionic conductivity, and dielectric investigations in K3H(SO4)2 single crystals
    Chen, RH
    Chang, RY
    Shern, CS
    Fukami, T
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (04) : 553 - 563
  • [50] Effect of temperature and high pressure on Mn2+ EPR spectra in K3H(SO4)2 fast-proton conductor
    Ostrowski, Adam
    Krupska, Aldona
    PHASE TRANSITIONS, 2006, 79 (6-7) : 569 - 575