Replacing Pd(OAc)2 with supported palladium nanoparticles in ortho-directed CDC reactions of alkylbenzenes

被引：15

作者：

Bao, Yong-Sheng ^{[1
]}

Zhang, Dongling ^{[1
]}

Jia, Meilin ^{[1
]}

Bao Zhaorigetu ^{[1
]}

机构：

[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Inner Mongolia Key Lab Green Catalysis, Hohhot 010022, Peoples R China

来源：

GREEN CHEMISTRY | 2016年 / 18卷 / 07期

基金：

美国国家科学基金会;

关键词：

H BOND ACYLATION; OXIDATIVE ORTHO-ACYLATION; C COUPLING REACTION; TOLUENE DERIVATIVES; CATALYTIC CYCLE; ACTIVATION; ALDEHYDES; FUNCTIONALIZATION; ACETANILIDES; AROYLATION;

D O I：

10.1039/c5gc02554k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supported palladium nanoparticles are used as efficient catalysts for the synthesis of aromatic ketones via cross dehydrogenative coupling reactions of 2-arylpyridines with alkylbenzenes. The catalyst can be reused for five cycles without significantly losing activity. Mechanism research showed that alkylbenzenes were oxidized to their corresponding aldehydes and subsequently coupled with 2-arylpyridines to generate aryl ketones through a Pd-0/Pd-II/Pd-IV catalytic cycle.

引用

页码：2072 / 2077

页数：6

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