Hydrothermal synthesis and characterization of a new hydrated ammonium barium thioarsenate:: (NH4)BaAsS4•2H2O

被引：0
|
作者：
Korzenski, MB [1 ]
Schimek, GL [1 ]
Kolis, JW [1 ]
机构：
[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
来源：
SOLID STATE SCIENCES | 2000年 / 2卷 / 03期
关键词：
hydrothermal; solvothermal; chalcogenides; thioarsenates;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new alkaline-earth thioarsenate, (NH4)BaAsS4 . 2H(2)O, has been prepared using low-temperature solvothermal methods and characterized by single-crystal X-ray diffraction, both infrared and diffuse reflectance spectroscopies, and thermogravimetric analysis. The title compound crystallizes as large transparent yellow columns in the space group Pnma (no. 62) with a = 11.890(3), b = 6.929(3), c = 12.095(4) Angstrom, V = 996.5(6) Angstrom(3) and Z = 4 with R/R-w = 0.0230/0.0307. The compound exhibits a low-dimensional structure built from barium interactions with discrete tetrahedral Ass, units, creating a framework in which the barium, ammonium cations and water molecules reside. Thermal analysis indicates the loss of both water and ammonia at relatively low temperatures. (C) 2000 Editions scientifiques et medicales Elsevier SAS. All rights reserved.
引用
收藏
页码：377 / 381
页数：5
相关论文
共 50 条
  • [21] Structure and spectral characteristics of (NH4)2[Re2(HPO4)4 • 2H2O]
    Shtemenko, A. V.
    Stolyarenko, V. G.
    Domasevich, K. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (07) : 1014 - 1019
  • [22] Synthesis and structure of (NH4)2[(UO2)2(C2O4)(CH3COO)4] • 2H2O
    Serezhkina, L. B.
    Vologzhanina, A. V.
    Neklyudova, N. A.
    Serezhkin, V. N.
    Antipin, M. Yu.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (08) : 1193 - 1196
  • [23] Structural investigations and thermal behavior of (NH4[Cr(C2O4)2]•2H2O
    Kahlenberg, V.
    Wertl, W.
    Kremenovic, A.
    Schuster, P.
    Schottenberger, H.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (05): : 921 - 926
  • [24] Structure and spectral characteristics of (NH4)2[Re2(HPO4)4 · 2H2O]
    A. V. Shtemenko
    V. G. Stolyarenko
    K. V. Domasevich
    Russian Journal of Inorganic Chemistry, 2006, 51 : 1014 - 1019
  • [25] Synthesis and structure of (NH4)2[(UO2)2(C2O4)(CH3COO)4] · 2H2O
    L. B. Serezhkina
    A. V. Vologzhanina
    N. A. Neklyudova
    V. N. Serezhkin
    M. Yu. Antipin
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1193 - 1196
  • [26] Crystal structure of NH4[UO2(C2O4)(NCS)] • 2H2O
    Artem'eva, MY
    Mikhailov, YN
    Gorbunova, YE
    Serezhkina, LB
    Serezhkin, VN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (09) : 1334 - 1336
  • [27] Synthesis and characterization of a new octamolybdate (NH4)4[Mo8O24(C3H2O2)2] • 4H2O
    Wang, Shoujiang
    Mo, Shaofen
    Liu, Zhen-Gang
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (03) : 430 - 433
  • [28] Synthesis and characterization of a new octamolybdate (NH4)4[Mo8O24(C3H2O2)2] · 4H2O
    Shoujiang Wang
    Shaofen Mo
    Zhen-Gang Liu
    Russian Journal of Inorganic Chemistry, 2012, 57 : 430 - 433
  • [29] Preparation and thermal decomposition of hexa-ammonium tetraphosphate dihydrate(NH4)6P4O13·2H2O
    A Takenaka
    Y Fukuma
    A Yasuda
    I Motooka
    H Nariai
    Journal of Materials Science, 1997, 32 : 3049 - 3053
  • [30] Crystal growth and optical properties of the polar hydrated pentaborates Rb[B5O6(OH)4] • 2H2O and NH4[B5O6(OH)2] • 2H2O and structure redetermination of the ammonium compound
    Becker, P
    Held, P
    Bohaty, L
    CRYSTAL RESEARCH AND TECHNOLOGY, 2000, 35 (11-12) : 1251 - 1262
12345