Electrical characterization of BaTiO3 and Ba0.77Ca0.23TiO3 ceramics It synthesized by the proteic sol-gel method

被引:17
|
作者
Sampaio, D., V [1 ]
Silva, M. S. [1 ,2 ]
Souza, N. R. S. [1 ]
Santos, J. C. A. [1 ]
Rezende, M. V. S. [1 ]
Silva, R. S. [1 ]
机构
[1] Univ Fed Sergipe, Dept Fis, Grp Nanomat Funcionais, BR-49100000 Sao Cristovao, SE, Brazil
[2] Inst Fed Educ Ciencia & Tecnol Sertao Pernambucan, BR-56000000 Salgueiro, PE, Brazil
关键词
Barium titante; Sol-gel; Coconut water; Barium calcium titanate; Ceramic; Electrical properties; PHASE-TRANSITION; RELAXATION; CALCIUM;
D O I
10.1016/j.ceramint.2018.05.213
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, we introduce a simple, low-cost, and ecofriendly method for producing barium titanate (BaTiO3-BT) and barium calcium titanate (Ba0.77Ca0.23TiO3-BCT) powders. The synthesis was performed by using a proteic sol-gel route which use coconut water in the polymerization step of the metallic precursor. We investigated the effects of the processing parameters with the density, microstructure, and (di)electric properties as sample quality indicators. The sintered ceramics exhibit single crystalline phase, relative density of 95%, a homogeneous microstructure, and an average grain size of 4 m. The respective dielectric constants of 1200 (BT) and 700 (BCT), measured at room temperature, and the activation energy values for the conductive process are according to those reported in the literature for conventionally prepared ceramics.
引用
收藏
页码:15526 / 15530
页数:5
相关论文
共 50 条
  • [21] Synthesis of non-agglomerated Ba0.77Ca0.23TiO3 nanopowders by a modified polymeric precursor method
    Ronaldo Santos da Silva
    Maria Inês Basso Bernardi
    Antonio Carlos Hernandes
    Journal of Sol-Gel Science and Technology, 2007, 42 : 173 - 179
  • [22] Synthesis of non-agglomerated Ba0.77Ca0.23TiO3 nanopowders by a modified polymeric precursor method
    da Silva, Ronaldo Santos
    Basso Bernardi, Maria Ines
    Hernandes, Antonio Carlos
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2007, 42 (02) : 173 - 179
  • [23] Structural and dielectric properties of Nd3+-doped Ba0.77Ca0.23TiO3 ceramics -: art. no. 104113
    Mazon, T
    Hernandes, AC
    Souza, AG
    Moraes, APA
    Ayala, AP
    Freire, PTC
    Mendes, J
    JOURNAL OF APPLIED PHYSICS, 2005, 97 (10)
  • [24] Manipulating the ferroelectric, dielectric and photoluminescence performance of Ba0.77Ca0.23TiO3 ceramics through Pr3+ ions doping
    Zhou, Luhui
    Du, Peng
    Zhang, Quan
    Zhu, Jiujun
    Hou, Yafei
    Luo, Laihui
    Li, Weiping
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 810
  • [25] Effect of pH-Induced Nanopowder Deagglomeration on Sintering, Microstructure and Dielectric Properties of Ba0.77Ca0.23TiO3 Ceramics
    da Silva, Ronaldo Santos
    Hernandes, Antonio Carlos
    M'Peko, Jean-Claude
    MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, 2012, 15 (04): : 522 - 529
  • [26] Experimental estimation of the bulk electric field and the photoconductivity of a Ba0.77Ca0.23TiO3 crystal (BCT)
    Matusevich, V
    Kiessling, A
    Kowarschik, R
    JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2002, 4 (04): : 377 - 381
  • [27] Electrical and structural characterization of PTCR pure BaTiO3 nanopowders synthesized by sol-gel emulsion technique
    Aga, Zubeda Bi H.
    Ramanan, Sutapa Roy
    JOURNAL OF ELECTROCERAMICS, 2012, 28 (2-3) : 109 - 117
  • [28] Sol-gel preparation and characterization of ultrafine BaTiO and semiconducting BaTiO3 ceramics doped with Yttrium
    Wu, Shurong
    Li, Huaping
    Chang, Zhuguo
    Liang, Wenzhong
    Xiong, Weimiao
    Gongneng Cailiao/Journal of Functional Materials, 1995, 25 (05): : 427 - 430
  • [29] Rheological characterization of the BaTiO3 sol-gel transition
    VanCantfort, O
    Brasseur, A
    Michaux, B
    Pirard, R
    Pirard, JP
    Lecloux, AJ
    FARADAY DISCUSSIONS, 1995, 101 : 265 - 274
  • [30] Experimental estimation of the internal electric field and the photoconductivity of a Ba0.77Ca0.23TiO3 crystal (BCT)
    Matusevich, V
    Kiessling, A
    Kowarschik, R
    ICONO 2001: NONLINEAR OPTICAL PHENOMENA AND NONLINEAR DYNAMICS OF OPTICAL SYSTEMS, 2002, 4751 : 252 - 264