Electrical characterization of BaTiO3 and Ba0.77Ca0.23TiO3 ceramics It synthesized by the proteic sol-gel method

被引:17
|
作者
Sampaio, D., V [1 ]
Silva, M. S. [1 ,2 ]
Souza, N. R. S. [1 ]
Santos, J. C. A. [1 ]
Rezende, M. V. S. [1 ]
Silva, R. S. [1 ]
机构
[1] Univ Fed Sergipe, Dept Fis, Grp Nanomat Funcionais, BR-49100000 Sao Cristovao, SE, Brazil
[2] Inst Fed Educ Ciencia & Tecnol Sertao Pernambucan, BR-56000000 Salgueiro, PE, Brazil
关键词
Barium titante; Sol-gel; Coconut water; Barium calcium titanate; Ceramic; Electrical properties; PHASE-TRANSITION; RELAXATION; CALCIUM;
D O I
10.1016/j.ceramint.2018.05.213
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, we introduce a simple, low-cost, and ecofriendly method for producing barium titanate (BaTiO3-BT) and barium calcium titanate (Ba0.77Ca0.23TiO3-BCT) powders. The synthesis was performed by using a proteic sol-gel route which use coconut water in the polymerization step of the metallic precursor. We investigated the effects of the processing parameters with the density, microstructure, and (di)electric properties as sample quality indicators. The sintered ceramics exhibit single crystalline phase, relative density of 95%, a homogeneous microstructure, and an average grain size of 4 m. The respective dielectric constants of 1200 (BT) and 700 (BCT), measured at room temperature, and the activation energy values for the conductive process are according to those reported in the literature for conventionally prepared ceramics.
引用
收藏
页码:15526 / 15530
页数:5
相关论文
共 50 条
  • [1] Ba0.77Ca0.23TiO3 (BCT):: a new photorefractive material to replace BaTio3 in applications
    Roosen, G
    Bernhardt, S
    Delaye, P
    OPTICAL MATERIALS, 2003, 23 (1-2) : 243 - 251
  • [2] Structural, electrical, luminescent, and magnetic properties of Ba0.77Ca0.23TiO3:Eu ceramics
    Yang, Qihua
    Fang, Liang
    Zheng, Fengang
    Shen, Mingrong
    MATERIALS CHEMISTRY AND PHYSICS, 2009, 118 (2-3) : 484 - 489
  • [3] Luminescence of Ba0.77Ca0.23TiO3:Cr
    Jastrabik, L
    Kapphan, SE
    Trepakov, VA
    Kudyk, IB
    Pankrath, R
    JOURNAL OF LUMINESCENCE, 2003, 102 : 657 - 662
  • [4] Dielectric and infrared response of Ba0.77Ca0.23TiO3
    Savinov, ME
    Trepakov, VA
    Kamba, S
    Kapphan, SE
    Petzelt, J
    Pankrath, R
    Kislova, IL
    Kutsenko, AB
    Jastrabik, L
    FERROELECTRICS, 2003, 295 : 625 - 632
  • [5] Light-induced charge transport in photorefractive BaTiO3:Fe and Ba0.77Ca0.23TiO3:Fe
    Mazur, A
    Veber, C
    Schirmer, OF
    Kuper, C
    Hesse, H
    RADIATION EFFECTS AND DEFECTS IN SOLIDS, 1999, 150 (1-4): : 281 - 286
  • [6] Aging effect of Mn-doped Ba0.77Ca0.23TiO3 ceramics
    Yue, Qingying
    Luo, Laihui
    Jiang, Xijie
    Li, Weiping
    Zhou, Jun
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 610 : 276 - 280
  • [7] Electrophoretic deposition of Ba0.77Ca0.23TiO3 nanopowders
    Antonelli, Eduardo
    Silva, Ronaldo Santos
    de Vicente, Fabio Simoes
    Zanatta, Antonio Ricardo
    Hernandes, Antonio Carlos
    JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2008, 203 (1-3) : 526 - 531
  • [8] Model of deep and shallow traps for the crystal Ba0.77Ca0.23TiO3
    V. Matusevich
    A. Kiessling
    R. Kowarschik
    Applied Physics B, 2001, 72 : 435 - 440
  • [9] Model of deep and shallow traps for the crystal Ba0.77Ca0.23TiO3
    Matusevich, V
    Kiessling, A
    Kowarschik, R
    APPLIED PHYSICS B-LASERS AND OPTICS, 2001, 72 (04): : 435 - 440
  • [10] High quality crystal growth and characterization of ferroelectric Ba0.77Ca0.23TiO3 single crystal
    Liu, Lei
    Yin, Fangyi
    Zhao, Guiyuan
    Zheng, Limei
    Fu, Xiuwei
    Jia, Zhitai
    Tao, Xutang
    JOURNAL OF ADVANCED DIELECTRICS, 2023, 13 (02)