CO2 Hydrates - Effect of Additives and Operating Conditions on the Morphology and Hydrate Growth

被引：22

作者：

Veluswamy, Hari Prakash ^{[1
]}

Premasinghe, Kulesha Priyalal ^{[1
]}

Linga, Praveen ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore

来源：

8TH INTERNATIONAL CONFERENCE ON APPLIED ENERGY (ICAE2016) | 2017年 / 105卷

基金：

新加坡国家研究基金会;

关键词：

gas hydrates; formation kinetics; carbon dioxide capture; hydrate morphology; promoter; CARBON-DIOXIDE; HYDROGEN STORAGE; NATURAL-GAS; KINETICS; CAPTURE; THF;

D O I：

10.1016/j.egypro.2017.03.1019

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this paper, we present the kinetics of CO2 hydrate formation in presence of additives at different operating conditions that result in the formation of pure sI hydrate, pure sII hydrates and a mixture of sI and sII hydrates. Visual observations of different hydrates formed are presented with the associated CO2 uptake achieved under different experimental conditions. We observe a striking contrast in hydrate formation behavior observed for CH4 hydrate and CO2 hydrate in presence of tetrahydrofuran (THF) under similar diving force and operating conditions. Based on our experiments, it can be inferred that hydrate formation kinetics in presence of the THF is highly influenced by the type of guest gas. (C) 2016 The Authors. Published by Elsevier Ltd.

引用

页码：5048 / 5054

页数：7

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