Di-μ1,1-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)]

被引:3
|
作者
Li, He-Bing [1 ]
机构
[1] Xiangnan Univ, Dept Chem & Life Sci, Chenzhou 423000, Peoples R China
关键词
MAGNETIC-PROPERTIES; STRUCTURAL-CHARACTERIZATION; AZIDO; COMPLEXES; BRIDGES;
D O I
10.1107/S1600536810017174
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the centrosymmetric binuclear title complex, [Cu-2(C13H19N2O)(2)(N-3)(2)], the Cu-II atom adopts an elongated CuON4 square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu center dot center dot center dot Cu separation is 3.2365 (3) angstrom. A pair of intramolecular N-H center dot center dot center dot O hydrogen bonds helps to establish the molecular conformation.
引用
收藏
页码:M651 / U529
页数:11
相关论文
共 50 条
  • [31] Di-μ-azido-bis{[1-(2-pyridylmethyliminomethyl)-2-naphtholato]zinc(II)}
    You, ZL
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2005, 61 : M432 - M434
  • [32] Bis[2-(o-tolyliminomethyl)phenolato]copper(II)
    Zhu, HL
    Cheng, K
    You, ZL
    Li, YG
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M755 - M756
  • [33] Di-μ-chlorido-bis[(2-{(E)-[(2,3-dihydroxypropyl)imino]methyl}phenolato)copper(II)] methanol monosolvate
    Li, Yong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1539 - +
  • [34] Bis{2-[1-(adamantan-1-yl)ethyliminomethyl]phenolato-κO}dichloromanganese(II)
    Huang, JL
    Wen, YH
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M611 - M612
  • [35] Bis[2-(1-naphthyliminomethyl)phenolato-κ2N,O]copper(II)
    Dong, Jian-Fang
    Li, Lian-Zhi
    Gao, Li-Wei
    Xu, Tao
    Wang, Da-Qi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1375 - M1376
  • [36] Di-μ-perchlorato-bis{μ-2-[(2-pyridyl)methylaminomethyl]phenolato)dicopper(II) acetonitrile disolvate
    Assey, Gervas E.
    Yisgedu, Teshome
    Gultneh, Yilma
    Butcher, Ray J.
    Tesema, Yohannes
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1007 - U1682
  • [37] Bis[2-(1H-benzimidazol-2-yl)phenolato]copper(II) dimethylformamide disolvate
    Xi, Y
    Li, J
    Zhang, FX
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1953 - M1954
  • [38] Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ2N,O1}copper(II)
    Dong, Wen-Kui
    Dong, Xiu-Yan
    Sun, Yin-Xia
    Wu, Jian-Chao
    Xing, Si-Jia
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1626 - U1315
  • [39] Bis{2-[1-(benzylimino)ethyl]-5-methoxyphenol}dichlorozinc(II)
    Xu, Xing-You
    Xu, Tong-Tao
    Ni, Shuai-Shuai
    Gao, Jian
    Wang, Da-Qi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M1548 - M1549
  • [40] Mono-, di- and trinuclear copper(II) dioxime complexes; 3-{2-[2-(2-hydroxyimino-1-methylpropylideneamino)ethylamino]ethylimino}butan-2-one oxime
    Kerim Serbest
    Serdar Karaböcek
    İsmail Değirmencioğlu
    Saadettin Güner
    Fatma Kormali
    Transition Metal Chemistry, 2001, 26 : 375 - 379