Activation of σ(C-H) bonds of [Fe{(η5-C5H4)-C(Me)=N-N= C(H)(C6H3-2,6-R)}2] (with R = Cl or H) promoted by palladium(II)

被引：12
|
作者：
López, C
Bosque, R
Arias, J
Evangelio, E
Solans, X
Font-Bardia, M
机构：
[1] Univ Barcelona, Fac Quim, Dept Quim Inorgan, Barcelona 08028, Spain
[2] Univ Barcelona, Fac Geog, Dept Cristalog Mineral & Diposits Minerals, Barcelona 08028, Spain
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 672卷 / 1-2期
关键词：
activation of C-H; iron; Schiff base; palladium;
D O I：
10.1016/S0022-328X(03)00137-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, characterisation and the study of the reactivity of the novel and bifunctional ferrocenyl Schiff bases [Fe{(eta(5)-C5H4)-C(Me)=N-N=C(H)(C6H3-2,6-R-2)}(2)] (with R = Cl or H) with palladium(II) salts under different experimental conditions are reported. The treatment of Na-2[PdCl4], Na(CH3COO) .3H(2)O and the corresponding ligand [Fe{(eta(5)-C5H4)-C(Me)=N-N= C(H)(C(6)H(3-)2,6-R-2)}(2)] (with R = Cl or H) (in a 2:2:1 molar ratio) in methanol for 6 days followed by the addition of triphenylphosphine (PPh3), and a SiO2 column chromatography, allowed the isolation of the two isomers (meso- and D,L- forms) of the heterotrimetallic complexes of general formula [Pd-2{Fe[(eta(5)-C5H3)-C(Me)=N-N=C(H)(C6H5-2,6-R-2)](2)}Cl-2(PPh3)(2)], (with R = Cl or H). (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：34 / 42
页数：9
相关论文
共 50 条
  • [31] DIPOLE OSCILLATOR STRENGTH DISTRIBUTIONS AND SUMS FOR C2H6, C3H8, N-C4H10, N-C5H12, N-C6H14, N-C7H16, AND N-C8H18
    JHANWAR, BL
    MEATH, WJ
    MACDONALD, JCF
    CANADIAN JOURNAL OF PHYSICS, 1981, 59 (02) : 185 - 197
  • [32] Ruthenium-mediated selective activation of a C-H bond, Direct aromatic thiolation in the complexes [RuII{o-SC6H3(R)N=NC5H4N} @2] (R = H, Me or Cl)
    J Chem Soc Dalton Trans, 1 (129):
  • [33] A metallocene with Ga-Zr bonds:: Cp2Zr(GaR)2 (Cp = C5H5;: R = -C6H3-2,6-(2,4,6-i-Pr3C6H2)2)
    Yang, XJ
    Quillian, B
    Wang, YZ
    Wei, PR
    Robinson, GH
    ORGANOMETALLICS, 2004, 23 (22) : 5119 - 5120
  • [34] Mechanistical studies on C-H activation reactions of benzaldimines using selectively deuterated ligands:: synthesis and crystal structures of [μ2-η3-(R)N-CH2-C=C- C(H)=C(H)-C(H)=C(H)]Fe2(CO)6
    Imhof, W
    Göbel, A
    Ohlmann, D
    Flemming, J
    Fritzsche, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 584 (01) : 33 - 43
  • [35] The spectroscopic consequences of C-H•••π H-bonding:: C6H6-(C4H2)n clusters with n=1 and 2
    Ramos, C
    Winter, PR
    Stearns, JA
    Zwier, TS
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (48): : 10280 - 10287
  • [36] Synthesis and structure characterization of [HgCl(η5-C5H3C(CH3)=N-3C5H4N)Fe(η5-C5H5)]•1/2CH2Cl2
    Lin, KH
    Song, MP
    Du, CX
    Zhang, QH
    Hao, XQ
    Wu, YJ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (01) : 15 - 18
  • [37] 5-Aminopyrazole Dimerization: Cu-Promoted Switchable Synthesis of Pyrazole-Fused Pyridazines and Pyrazines via Direct Coupling of C-H/N-H, C-H/C-H, and N-H/N-H Bonds
    Chai, Yi-Xin
    Ren, Jun-Jie
    Li, Yi-Ming
    Bai, Yi-Cheng
    Zhang, Qing-Qing
    Zhao, Yi-Zhen
    Yang, Xue
    Zhang, Xiao-Han
    Zhang, Xin-Shuang
    Wu, An-Xin
    Zhu, Yan-Ping
    Sun, Yuan-Yuan
    MOLECULES, 2025, 30 (02):
  • [38] Crystal Packing of Potentially Mesomorphic Azobenezene Derivatives R1–C6H4–N=N–C6H4–R2 (R1, R2 = CH3COO, C2H5O; CH2=C(CH3)COO, C2H5; C6H13COO, C2H5O)
    L. G. Kuz’mina
    I. I. Konstantinov
    M. A. Navasardyan
    Crystallography Reports, 2020, 65 : 436 - 443
  • [39] ON THE STRUCTURE OF C4H4+ PRODUCED IN THE UNIMOLECULAR FRAGMENTATION OF C6H6+ AND C5H5N+
    AUSLOOS, P
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (13) : 3931 - 3932
  • [40] The Synthesis of the Arene Clusters Ru6C(CO)14(η6-Arene) (Arene = C6H5CHMe2, C6H5C4H9, C6H5C3H7, and C6H5C3H5)
    Dyson P.J.
    Gaede P.E.
    Johnson B.F.G.
    McGrady J.E.
    Parsons S.
    Journal of Cluster Science, 1997, 8 (4) : 533 - 545
12345