Pervaporative transport mechanisms in phosphonium ionic liquid-based supported liquid membrane and its stability with actual fermentation broth feed

被引：2

作者：

Cascon, Hercules R. ^{[1
]}

Choudhari, Santosh K. ^{[2
]}

机构：

[1] Xavier Univ Ateneo de Cagayan, Dept Chem Engn, Corrales Ave, Cagayan De Oro 9000, Philippines

[2] Dayananda Sagar Univ, Sch Basic & Appl Sci, Dept Biol Sci, Bangalore, Karnataka, India

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 2017年 / 52卷 / 12期

关键词：

1-butanol; ABE fermentation broth; ionic liquid; pervaporation; SILM; ACTIVITY-COEFFICIENTS; INFINITE DILUTION; WATER; SYSTEMS; SEPARATION; ACID; PERFORMANCE; COMPONENTS; ETHANOL; BINARY;

D O I：

10.1080/01496395.2017.1309431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pervaporative transport interactions between trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)imide ionic liquid-based membrane and the components of ABE fermentation broth were elucidated in this study. Acetone has a suggested viscosity decreasing effect on the ionic liquid and exhibited coupling effect with 1-butanol. Temperature increase consistently caused increase on 1-butanol permeance. The presence of acetic and butyric acids has no observed effect on 1-butanol and water permeation. No permeation of ethanol and acetic acid was noted, while butyric acid permeation can be suppressed by pH control. The membrane was proven stable in separating 1-butanol from actual fermentation broth for long period of time.

引用

页码：2029 / 2039

页数：11

共 50 条

[41] Green imidazolium ionic liquid selectively facilitates Ce(III) ion transport through supported liquid membrane
Asadollahzadeh, Mehdi
Torkaman, Rezvan
Torab-Mostaedi, Meisam
Ghaemi, Ahad
Hemmati, Alireza
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2022, 102 (16) : 4814 - 4829
[42] Vegetable Oil-Ionic Liquid-Based Emulsion Liquid Membrane for the Removal of Lactic Acid from Aqueous Streams: Emulsion Size, Membrane Breakage, and Stability Study
Khan, Huma Warsi
Elgharbawy, Amal A. M.
Bustam, Mohamed Azmi
Goto, Masahiro
Moniruzzaman, Muhammad
ACS OMEGA, 2022, 7 (36): : 32176 - 32183
[43] Enhanced energy transfer efficiency and stability of europium β-diketonate complex in ionic liquid-based lyotropic liquid crystals
Yi, Sijing
Wang, Jiao
Chen, Xiao
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (31) : 20322 - 20330
[44] Dispersion of multi-walled carbon nanotubes (MWCNTs) by ionic liquid-based phosphonium surfactants in aqueous solution
Lu, Fei
Zhang, Shaohua
Zheng, Liqiang
JOURNAL OF MOLECULAR LIQUIDS, 2012, 173 : 42 - 46
[45] One step selective partition of ε-polylysine present in broth cultures in ionic liquid-based aqueous biphasic systems
Sequeira, Rosy Alphons
Sharma, Mukesh
Pereira, Matheus M.
Singh, Nripat
Bhattacharya, Sourish
Chudasama, Nishith A.
Prasad, Kamalesh
SEPARATION SCIENCE AND TECHNOLOGY, 2021, 56 (03) : 631 - 639
[46] Studies on ionic liquid-based corn starch biopolymer electrolytes coupling with high ionic transport number
Liew, Chiam-Wen
Ramesh, S.
CELLULOSE, 2013, 20 (06) : 3227 - 3237
[47] Solute transport from aqueous mixture throught supported ionic liquid membrane by pervaporation
Izak, Pavel
Koekerling, A.
Kragl, U.
DESALINATION, 2006, 199 (1-3) : 96 - 98
[48] One step selective partition of Ε-polylysine present in broth cultures in ionic liquid-based aqueous biphasic systems
Sequeira, Rosy Alphons
Sharma, Mukesh
Pereira, Matheus M.
Singh, Nripat
Bhattacharya, Sourish
Chudasama, Nishith A
Prasad, Kamalesh
Separation Science and Technology (Philadelphia), 2021, 56 (03): : 631 - 639
[49] Studies on ionic liquid-based corn starch biopolymer electrolytes coupling with high ionic transport number
Chiam-Wen Liew
S. Ramesh
Cellulose, 2013, 20 : 3227 - 3237
[50] Lithium Recovery from Seawater by Electrodialysis using Ionic Liquid-based Membrane Technology
Hoshino, T.
LITHIUM-ION BATTERIES, 2014, 58 (48): : 173 - 177

← 1 2 3 4 5 →