N-Hydroxy sulfonamides as new sulfenylating agents for the functionalization of aromatic compounds

被引：39
|
作者：
Wang, Fu-Xiang
Zhou, Shao-Da
Wang, Chengming
Tian, Shi-Kai [1 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 25期
基金：
中国国家自然科学基金;
关键词：
CATALYZED REGIOSELECTIVE SULFENYLATION; ONE-POT SYNTHESIS; METAL-FREE SULFENYLATION; C-H THIOLATION; SULFONYL HYDRAZIDES; CONTROLLABLE SYNTHESIS; PROPARGYLIC ALCOHOLS; NITRIC-OXIDE; INDOLES; EFFICIENT;
D O I：
10.1039/c7ob01390f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An unprecedented use of N-hydroxy sulfonamides as sulfenylating agents has been established. In the presence of catalytic amounts of iodine and N-hydroxysuccinimide, N-hydroxy sulfonamides participated in sulfenylation with indoles, 7-azaindole, N-methyl pyrrole, and 2-naphthol to afford structurally diverse thioethers in moderate to excellent yields with very high regioselectivity.
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页码：5284 / 5288
页数：5
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