Organic/inorganic hybrid materials and nanocomposites based upon layered silicates modified with cyclic amidines

被引：0

作者：

Zilg, C

Thomann, R

Baumert, M

Finter, J

Mülhaupt, R

机构：

[1] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany

[2] Elf Atochem, Res & Dev Ctr, F-27470 Serquigny, France

[3] Ciba Specialty Chem, Performance Polymers Div, CH-4002 Basel, Switzerland

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2000年 / 21卷 / 17期

关键词：

D O I：

10.1002/1521-3927(20001101)21:17<1214::AID-MARC1214>3.3.CO;2-S

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various cyclic amidinium cations were used to exchange intergallery sodium cations of water-swellable fluorohectorite in order to produce novel families of organic/inorganic hybrid materials. Oligomeric cyclic amidinium cations, such as mono(imidazolinium)terminated oligostyrene, oligostyrene-co-oligo(acrylonitrile), and oligo(methyl methacrylate) with number-average molecular masses around 3000 g/mol afforded effective exfoliation during melt processing. Morphology and dynamic mechanical properties were measured as a function of silicate content and silicate modification.

引用

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页码：1214 / 1219

页数：6

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