Kinetics study on catalytic wet air oxidation of phenol

被引：44

作者：

Wu, Q ^{[1
]}

Hu, XJ ^{[1
]}

Yue, PL ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem Engn, Kowloon, Hong Kong, Peoples R China

来源：

CHEMICAL ENGINEERING SCIENCE | 2003年 / 58卷 / 3-6期

关键词：

wet air oxidation; homogeneous catalyst; free radical; kinetics; reaction engineering; simulation;

D O I：

10.1016/S0009-2509(02)00628-0

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A kinetics study on the phenol oxidation by catalytic wet air oxidation (CWAO) using aqueous copper nitrate as homogeneous catalyst is presented. Based on the free radical mechanism a kinetics model is established where the electron transfer from copper to phenol is assumed to initiate the formation of free radicals. According to this model, the reaction orders are found to be approximately 1.0, 0.5 and 0.5 with respect to phenol, oxygen and copper concentrations, respectively. In order to verify the proposed kinetics, a series of CWAO experimental tests were done at various temperatures (313-333 K), oxygen partial pressures (0.6-1.9 MPa), and copper concentrations (0-13 mg1(-1)). The experimental data were found to agree well with the model. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：923 / 928

页数：6

共 50 条

[41] Preparing and characterizing an optimal supported ceria catalyst for the catalytic wet air oxidation of phenol
Chen, IP
Lin, SS
Wang, CH
Chang, L
Chang, JS
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 50 (01) : 49 - 58
[42] The Catalytic Wet Air Oxidation of Phenol with Fe2O3 Nanoparticles
Cui, Duo Heng
Wan, Yue
Song, Xu Chun
[J]. PROCEEDINGS OF THE 2015 INTERNATIONAL CONFERENCE ON COMPUTER SCIENCE AND ENGINEERING TECHNOLOGY (CSET2015), MEDICAL SCIENCE AND BIOLOGICAL ENGINEERING (MSBE2015), 2016, : 676 - 681
[43] Rectorite as catalyst for wet air oxidation of phenol
Xu, Aihua
Yang, Min
Yao, Huiqiang
Du, Hongzhang
Sun, Chenglin
[J]. APPLIED CLAY SCIENCE, 2009, 43 (3-4) : 435 - 438
[44] Wet air oxidation of nitrobenzene enhanced by phenol
Fu, DM
Chen, JP
Liang, XM
[J]. CHEMOSPHERE, 2005, 59 (06) : 905 - 908
[45] Heteroatom (N, S) Co-Doped CNTs in the Phenol Oxidation by Catalytic Wet Air Oxidation
Rocha, Raquel P.
Soares, Olivia Salome G. P.
Orfao, Jose J. M.
Pereira, Manuel Fernando R.
Figueiredo, Jose L.
[J]. CATALYSTS, 2021, 11 (05)
[46] Study on Catalytic Wet Air Oxidation Process for Phenol Degradation in Synthetic Wastewater Using Trickle Bed Reactor
Mohammad F. Abid
Ghanim M. Alwan
Lamyaa A. Abdul-Ridha
[J]. Arabian Journal for Science and Engineering, 2016, 41 : 2659 - 2670
[47] Study on Catalytic Wet Air Oxidation Process for Phenol Degradation in Synthetic Wastewater Using Trickle Bed Reactor
Abid, Mohammad F.
Alwan, Ghanim M.
Abdul-Ridha, Lamyaa A.
[J]. ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2016, 41 (07) : 2659 - 2670
[48] Catalytic wet air oxidation of wastewaters
Beziat, JC
Besson, M
Gallezot, P
Juif, S
Durecu, S
[J]. 3RD WORLD CONGRESS ON OXIDATION CATALYSIS, 1997, 110 : 615 - 622
[49] Wet Air Oxidation and Catalytic Wet Air Oxidation for Refinery Spent Caustics Degradation
Chen, Chen
Cheng, Ting
[J]. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2013, 35 (02): : 243 - 249
[50] Degradation of paracetamol by catalytic wet air oxidation and sequential adsorption - Catalytic wet air oxidation on activated carbons
Quesada-Penate, I.
Julcour-Lebigue, C.
Jauregui-Haza, U. J.
Wilhelm, A. M.
Delmas, H.
[J]. JOURNAL OF HAZARDOUS MATERIALS, 2012, 221 : 131 - 138

← 1 2 3 4 5 →