Osmium(VIII) - Catalyzed oxidation of some cyclic amines by potassium hexacyanoferrate(III) in alkaline media: A kinetics and mechanistic study

被引：0

作者：

Al-Subu, MM ^{[1
]}

Jondi, WJ

Amer, AA

Hannoun, M

Musmar, MJ

机构：

[1] An Najah Natl Univ, Dept Chem, Nablus, Palestinian Aut, Israel

[2] An Najah Natl Univ, Coll Pharm, Nablus, Palestinian Aut, Israel

来源：

KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII | 2003年 / 04期

关键词：

morpholine; piperidine; piperazine; Os(VIII); hexacyanoferrate(III); lactam; kinetics; oxidation;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of morpholine, piperidine and piperazine with Os(VIII) catalyzed hexacyanoferrate(III) in alkaline media to produce the corresponding lactam have been studied at constant temperature and ionic strength. The reactions followed first order kinetics with respect to [amine] and [Os(VIII)] but were independent of [Fe(CN)(6)(3-)] and [OH-]. The effects of introduced electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. A mechanism accounting for these results has been proposed.

引用

页码：559 / 565

页数：7

共 50 条

[11] KINETICS AND MECHANISM OF OS(VIII) CATALYZED OXIDATION OF CINNAMATE ION BY ALKALINE POTASSIUM HEXACYANOFERRATE (III)
KUMAR, S
MATHUR, PC
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1979, 41 (04): : 599 - 602
[12] Osmium(VIII) catalyzed oxidation of an antibiotic drug chloramphenicol by hexacyanoferrate(III) in aqueous alkaline medium: A mechanistic approach
Budri, Mahantesh B.
Mangalgatti, Zahiruddin A.
Hullur, Megharaj B.
Meti, Manjunath D.
Nandibewoor, Sharanappa T.
Chimatadar, Shivamurti A.
MAIN GROUP CHEMISTRY, 2013, 12 (01) : 1 - 14
[13] KINETICS AND MECHANISM OF RU(VIII) CATALYZED OXIDATION OF DULCITOL AND XYLITOL BY HEXACYANOFERRATE(III) IN ALKALINE MEDIA
SINGH, MP
KOTHARI, S
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1983, 22 (08): : 697 - 698
[14] OSMIUM(VIII)-CATALYZED OXIDATION OF ALLYL ALCOHOL BY HEXACYANOFERRATE(III) IN ALKALINE-MEDIUM
MORAB, VA
TUWAR, SM
NANDIBEWOOR, ST
RAJU, JR
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1992, 69 (12) : 862 - 864
[15] KINETICS AND MECHANISMS OF OXIDATION BY METAL-IONS .11. KINETICS OF THE OSMIUM(VIII)-CATALYZED OXIDATION OF GLYCOLS BY ALKALINE HEXACYANOFERRATE(III)
KAPOOR, RC
MEHROTRA, RN
VAJPAI, SK
CHAUDHARY, P
TRANSITION METAL CHEMISTRY, 1991, 16 (01) : 65 - 70
[16] Mechanistic Studies of Osmium(VIII) Catalysed Oxidation of Sulfanilic Acid by Hexacyanoferrate (III) in Alkaline Medium
Sairabanu A. Farokhi
Sharanappa T. Nandibewoor
Catalysis Letters, 2009, 129 : 207 - 214
[17] Mechanistic Studies of Osmium(VIII) Catalysed Oxidation of Sulfanilic Acid by Hexacyanoferrate (III) in Alkaline Medium
Farokhi, Sairabanu A.
Nandibewoor, Sharanappa T.
CATALYSIS LETTERS, 2009, 129 (1-2) : 207 - 214
[18] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of hypophosphite by hexacyanoferrate(III) in aqueous alkali
Dubey, S
Sharma, N
Khandelwal, CL
Sharma, PD
TRANSITION METAL CHEMISTRY, 2003, 28 (02) : 176 - 181
[19] KINETICS AND MECHANISMS OF OXIDATION BY METAL-IONS .13. OSMIUM(VIII) CATALYZED OXIDATION OF CYCLOALKANOLS BY ALKALINE HEXACYANOFERRATE(III)
MEHTA, SPS
MEHROTRA, RN
TRANSITION METAL CHEMISTRY, 1991, 16 (04) : 402 - 406
[20] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of hypophosphite by hexacyanoferrate(III) in aqueous alkali
Sapna Dubey
Neetu Sharma
Chandra L. Khandelwal
Prem D. Sharma
Transition Metal Chemistry, 2003, 28 : 176 - 181

← 1 2 3 4 5 →