Synthesis and electronic properties of 9,10-disilylanthracenes

被引:114
|
作者
Kyushin, S
Ikarugi, M
Goto, M
Hiratsuka, H
Matsumoto, H
机构
[1] GUNMA UNIV,FAC ENGN,DEPT APPL CHEM,KIRYU,GUMMA 376,JAPAN
[2] NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN
关键词
D O I
10.1021/om950776m
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The sila-functional 9,10-disilylanthracenes An(SiR(2)X)(2) (1, R = i-Pr, X = H; 2, R = i-Pr, X = Cl; 3, R = Me, X = H) were synthesized and the X-ray structure is reported for 1. Compounds 1-3 as well as the related compound An(SiMe(3))(2) exhibit intense fluorescence (Phi(f) > 0.9) at room temperature.
引用
收藏
页码:1067 / 1070
页数:4
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