High-Pressure Synthesis of Superconducting Sn3S4 Using a Diamond Anvil Cell with a Boron-Doped Diamond Heater

被引:6
|
作者
Matsumoto, Ryo [8 ]
Terashima, Kensei [1 ]
Nakano, Satoshi [2 ]
Nakamura, Kazuki [1 ,3 ]
Yamamoto, Sayaka [1 ,3 ]
Yamamoto, Takafumi D. [1 ]
Ishikawa, Takahiro [4 ]
Adachi, Shintaro [5 ]
Irifune, Tetsuo [6 ]
Imai, Motoharu [7 ]
Takano, Yoshihiko [1 ,3 ]
机构
[1] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050047, Japan
[2] Natl Inst Mat Sci, Res Ctr Funct Mat, Tsukuba, Ibaraki 3050044, Japan
[3] Univ Tsukuba, Tsukuba, Ibaraki 3058577, Japan
[4] Natl Inst Mat Sci, Elements Strategy Initiat Ctr Magnet Mat ESICMM, Tsukuba, Ibaraki 3050047, Japan
[5] Kyoto Univ Adv Sci, Nagamori Inst Actuators, Ukyo Ku, Kyoto 6158577, Japan
[6] Ehime Univ, Geodynam Res Ctr GRC, Matsuyama, Ehime 7908577, Japan
[7] Natl Inst Mat Sci, Res Ctr Funct Mat, Tsukuba, Ibaraki 3050047, Japan
[8] Natl Inst Mat Sci, Int Ctr Young Scientists ICYS, Tsukuba, Ibaraki 3050047, Japan
关键词
POLYCRYSTALLINE DIAMOND; TRANSITION-TEMPERATURE; BILAYER SNS2; CRYSTAL;
D O I
10.1021/acs.inorgchem.2c00013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
High-pressure techniques open exploration of functional materials in broad research fields. An established diamond anvil cell with a boron-doped diamond heater and transport measurement terminals has performed the high-pressure synthesis of a cubic Sn3S4superconductor.X-ray diffraction and Raman spectroscopy reveal that the Sn3S4phase is stable in the pressure range of P> 5 GPa in a decompression process. Transport measurement terminals in the diamond anvil cell detect a metallic nature and superconductivity in the synthesized Sn3S4with a maximum onset transition temperature (Tconset) of 13.3 K at 5.6 GPa. The observed pressure-Tc relationship is consistent with that from the first-principles calculation. The observation of superconductivity in Sn3S4opens further materials exploration under high-temperature and -pressure conditions
引用
收藏
页码:4476 / 4483
页数:8
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