Syntheses, structures and third-order non-linear optical properties of homometal clusters containing molybdenum

被引：7
|
作者：
Li, Y
Lu, J
Cui, XB
Xu, JQ
Li, KC
Sun, HY
Li, GH
Pan, LY
Yang, QX
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
[4] Jilin Univ, Coll Phys, Changchun 130023, Jilin, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 01期
基金：
中国国家自然科学基金;
关键词：
molybdenum(V) clusters; solid-state reactions; third-order non-linear optical properties;
D O I：
10.1016/j.jssc.2004.11.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Both the homometal cluster [P(ph(4))](2)[Mo2O2(mu-S)(2)(S-2)(2)] (1) and [Mo2O2(mu-S)(2)(Et(2)dtc)(2)] (2) (Et(2)dtc = diethyl-dithiocarbamate) were successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies suggest that compound (1) is a dinuclear anion cluster, and compound (2) is a dinuclear neutral cluster. The two compounds were characterized by elemental analyses, IR spectra and UV-Vis spectra. The third-order non-linear optical (NLO) properties of the clusters were also investigated and all exhibited nice non-linear absorption and self-defocusing performance with moduli of the hyperpolarizabilities 5.145 x 10(-30) esu for (1) and 5.428 x 10(-30) esu for (2). (C) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码：363 / 369
页数：7
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