Impedance of a passive iron electrode in a solution containing a reducing agent

被引：3
|
作者：
Klyuev, AL
Rotenbergb, ZA
Batrakov, VV
机构：
[1] Russian Acad Sci, Frumkin Inst Electrochem, Moscow 119071, Russia
[2] Moscow State Pedag Univ, Moscow 119882, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2005年 / 41卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
impedance; passive iron electrode;
D O I：
10.1007/s11175-005-0010-6
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Frequency dependences of impedance of a passive iron electrode in 0.5 M Na2SO4 solutions with and without 0.01 M K-4[Fe(CN)(6)] are obtained by a pulsed method and the Fourier transform. At 1-1000 Hz, the results in 0.5 M Na2SO4 satisfactorily agree with our previous results obtained by a lock-in method. With the [Fe(CN)(6)](4-) ions present, the impedance decreases faster at lower frequencies. The impedance of the oxide film/solution interface relaxes longer the film impedance. These conclusions are similar to those obtained earlier.
引用
收藏
页码：87 / 90
页数：4
相关论文
共 50 条
  • [31] Passive Impedance Matching for Implanted Brain-Electrode Interfaces
    Chen, Wei-Chuan
    Guido, Katrina
    Kiourti, Asimina
    IEEE JOURNAL OF ELECTROMAGNETICS RF AND MICROWAVES IN MEDICINE AND BIOLOGY, 2019, 3 (04): : 233 - 239
  • [32] FLEXICOKE AS IRON-ORE REDUCING AGENT
    SPECHT, MI
    SEATON, C
    MORALES, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 110 - FUEL
  • [33] REDUCING ELECTRODE MOTION ARTIFACTS IN ELECTRICAL-IMPEDANCE PNEUMOGRAPHY
    SAHAKIAN, AV
    TOMPKINS, WJ
    WEBSTER, JG
    IEEE TRANSACTIONS ON BIOMEDICAL ENGINEERING, 1984, 31 (08) : 570 - 570
  • [34] IMPEDANCE OF IRON ELECTRODE PASSIVATED IN BORATE AND PHOSPHATE SOLUTIONS
    AZUMI, K
    OHTSUKA, T
    SATO, N
    TRANSACTIONS OF THE JAPAN INSTITUTE OF METALS, 1986, 27 (05): : 382 - 392
  • [35] IMPEDANCE OF IRON ELECTRODE PASSIVATED IN BORATE AND PHOSPHATE SOLUTIONS
    AZUMI, K
    OHTSUKA, T
    SATO, N
    JOURNAL OF THE JAPAN INSTITUTE OF METALS, 1985, 49 (09) : 729 - 736
  • [36] SELECTION OF A MODEL FOR THE IMPEDANCE OF HYDROGEN EVOLUTION AT THE IRON ELECTRODE
    KUZNETSOV, AA
    SOVIET ELECTROCHEMISTRY, 1986, 22 (10): : 1279 - 1285
  • [37] CAPACITANCE OF A PASSIVE IRON ELECTRODE IN ACIDIC SOLUTIONS.
    Grilikhes, M.S.
    Sapelova, E.V.
    Berezin, M.Yu.
    Gorlin, A.V.
    Sokolov, M.A.
    Sukhotin, A.M.
    1600, (21):
  • [38] RESISTOMETRIC STUDY OF PASSIVE FILM ON AN EVAPORATED IRON ELECTRODE
    TSURU, T
    HARUYAMA, S
    CORROSION SCIENCE, 1976, 16 (09) : 623 - 635
  • [39] THE IMPEDANCE SPECTRUM OF THE AGI ELECTRODE IN AQUEOUS-SOLUTION
    POLDER, RB
    BIJSTERBOSCH, BH
    VANLEEUWEN, HP
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 170 (1-2): : 175 - 193
  • [40] IMPEDANCE OF CoSi-ELECTRODE IN SODIUM HYDROXIDE SOLUTION
    Panteleeva, V. V.
    Shein, A. B.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2013, 56 (04): : 59 - +
12345