Novel addition reactions of titanacycle phosphonates by tuning of Ti(O-i-Pr)4/2i-PrMgCl

被引:24
|
作者
Quntar, AA [1 ]
Srebnik, M [1 ]
机构
[1] Hebrew Univ Jerusalem, Sch Pharm, Dept Med Chem & Nat Prod, IL-91120 Jerusalem, Israel
关键词
D O I
10.1039/b209149f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Di- or tri-substituted vinylphosphonates, 2-5, can be obtained in a highly regio- and stereoselective manner from 1-alkynylphosphonates, by manipulation of Ti(O-i-Pr)(4)/2i-PrMgCl.
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页码:58 / 59
页数:2
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