Effect of metal formiates and oxalates on HMX decomposition

被引:10
|
作者
Stepanov, RS [1 ]
Kruglyakova, LA [1 ]
Astakhov, AM [1 ]
Pekhotin, KV [1 ]
机构
[1] Siberian State Technol Univ, Krasnoyarsk 660049, Russia
关键词
thermal decomposition; metal formiates and oxalates; HMX; combustion modifiers;
D O I
10.1023/B:CESW.0000041410.25641.cc
中图分类号
O414.1 [热力学];
学科分类号
摘要
Metal formiates and oxalates applied onto HMX increase the initial rate and decrease the induction period of thermal decomposition of HMX. The activity of sodium oxalates, which contain crystal water, is much lower than that of anhydrous formiates of the same metals. The possible reasons of the catalytic effect of the additives on the thermal decomposition of are discussed.
引用
收藏
页码:576 / 579
页数:4
相关论文
共 50 条
  • [31] Synergistic Catalytic Effect of Thermite Nanoparticles on HMX Thermal Decomposition
    Sherif Elbasuney
    M. Yehia
    Abdelaziz Hamed
    Mohamed Mokhtar
    Mohamed Gobara
    Ahmed Saleh
    Eslam Elsaka
    Gharieb S. El-Sayyad
    Journal of Inorganic and Organometallic Polymers and Materials, 2021, 31 : 2293 - 2305
  • [32] Effect of preparation methods on mechanical sensitivity and thermal decomposition of HMX
    Song, Xiao-Lan
    An, Chong-Wei
    Guo, Xiao-De
    Liu, Hong-Ying
    Zhang, Jing-Lin
    Li, Feng-Sheng
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2008, 16 (06): : 698 - 702
  • [33] Catalytic Decomposition Kinetics of HMX in Solid Phase with Two Nano Metal Powders
    Liu W.-L.
    Gu Y.
    Yu S.-L.
    Zhang L.-J.
    Huozhayao Xuebao/Chinese Journal of Explosives and Propellants, 2020, 43 (04): : 413 - 418
  • [34] THE THERMAL-DECOMPOSITION OF OXALATES .18. THE PREPARATION AND THERMAL-DECOMPOSITION OF ACID BARIUM OXALATES
    BHATTI, AS
    DOLLIMORE, D
    FLETCHER, A
    THERMOCHIMICA ACTA, 1984, 78 (1-3) : 63 - 70
  • [35] CHROMATOGRAPHIC STUDY OF THE PROCESS OF THERMAL-DECOMPOSITION OF METALS FORMIATES
    DUCHINSKY, YS
    KUZYAKIN, EB
    PASALSKY, BK
    UKRAINSKII KHIMICHESKII ZHURNAL, 1987, 53 (07): : 697 - 699
  • [36] Mechanochemical decomposition of Ag and Ni oxalates
    Delogu, Francesco
    MATERIALS CHEMISTRY AND PHYSICS, 2014, 147 (03) : 629 - 635
  • [37] THERMAL DECOMPOSITION OF IRON(III) OXALATES
    RIGGS, WM
    BRICKER, CE
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (06): : 1634 - &
  • [38] THE THERMAL DECOMPOSITION OF ERBIUM AND LUTETIUM OXALATES
    GLASNER, A
    STEINBERG, M
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 22 (1-2): : 156 - 159
  • [39] Thermal decomposition of metal oxalates: Project laboratories that incorporate thermal analysis throughout the curriculum
    Warnaar, Deborah L.
    DeVore, Thomas C.
    Reisner, Barbara A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U766 - U766
  • [40] THE THERMAL-DECOMPOSITION OF CHROMIUM OXALATES
    BHATTI, AS
    DOLLIMORE, D
    ALMARZOOQI, M
    OHIO JOURNAL OF SCIENCE, 1984, 84 (02) : 36 - 36