Synthesis and Structure of [Er4(μ3-OH)4(Hpro)4(pro)2(H2O)7](ClO4)6•7H2O

被引：0
|
作者：
Hu, SM [1 ]
Du, WX [1 ]
Xia, SQ [1 ]
Fu, RB [1 ]
Zhang, JJ [1 ]
Wu, XT [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2003年 / 22卷 / 03期
关键词：
erbium; proline; cubane structure; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound [Er-4(mu(3)-OH)(4)(Hpro)(4)(pro)(2)(H2O)(7)](ClO4)(6).7H(2)O has been synthesized and its crystal structure was determined by X-ray diffraction study. It crystallizes in rhombohedral, space group R3, a = b = c = 12.7812(2) Angstrom, alpha = beta = gamma = 100.067(1)degrees, V = 1978.19(5) Angstrom(3), Z = 1, M-r = 2274.77, D-c = 1.909 g/cm(3), F(000) = 1112, mu = 4.506mm(-1), the final R = 0.0405 and wR = 0.1068 for 3711 observed reflections (I > 2sigma(I)). Four Er3+ ions and four mu(3)-OH display a Er4O4 cubane structural motif. Each proline interconnects two Er3+ ions.
引用
收藏
页码：309 / 312
页数：4
相关论文
共 50 条
  • [11] Synthesis and Crystal Structure of an Erbium Complex with Valine [Er2(Val)4(H2O)8](ClO4)6·4H2O
    杨维春
    王瑞瑶
    金天柱
    周忠远
    周向革
    JournalofRareEarths, 1998, (02) : 66 - 69
  • [12] Synthesis and crystal structure of an erbium complex with valine [Er2(Val)4(H2O)8](ClO4)6•4H2O
    Yang, WC
    Wang, RY
    Jin, TZ
    Zhou, ZY
    Zhou, XG
    JOURNAL OF RARE EARTHS, 1998, 16 (02) : 145 - 148
  • [13] CRYSTAL STRUCTURE OF COMPLEX OF ERBIUM（Ⅲ） AND QLYCINE,[Er（GLy）2（H2O）4]2（ClO4）6·4（C4H8O2）
    Zheng Yifan Pan KezhenFujian Institute of Research on the Structure of Matter
    结构化学, 1987, (02) : 132 - 134
  • [14] Synthesis and Crystal Structure of [Cu（phen）2（SO4）(H2O)]·0.5C4H4O4·7H2O
    王小琴
    温一航
    康遥
    张健
    程建开
    李兆基
    姚元根
    Chinese Journal of Structural Chemistry, 2006, (01) : 17 - 20
  • [15] Synthesis and crystal structure of [Cu(phen)2(SO4)(H2O)]•0.5C4H4O4•7H2O
    Wang, XQ
    Wen, YH
    Kang, Y
    Zhang, J
    Cheng, HK
    Li, ZJ
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (01) : 17 - 20
  • [16] 高pH下钇—L-脯氨酸四核配合物[Y4（HPrO）4（PrO）2（μ3-OH）4（H2O）7]（ClO4）6·6H2O的合成与晶体结构
    陈德
    张大顺
    李琳
    马宝清
    金天柱
    常德师范学院学报(自然科学版), 2000, (02) : 14 - 15+45
  • [17] Phase transitions of polycrystalline [Fe(H2O)6](ClO4)3 and [Cr(H2O)6](ClO4)3 studied by DSC
    E. Mikuli
    B. Grad
    K. Zaremba
    S. Wróbel
    Journal of Thermal Analysis and Calorimetry, 2004, 76 : 719 - 726
  • [18] Phase transitions of polycrystalline [Fe(H2O)6](ClO4)3 and [Cr(H2O)6](ClO4)3 studied by DSC
    Mikuli, E
    Grad, B
    Zaremba, K
    Wróbel, S
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 76 (03) : 719 - 726
  • [19] Synthesis and structure determination of lanthanum complex with β-alanine {[La2(β-ala)6(H2O)4](ClO4) Synthesis and structure determination of lanthanum complex with β-alanine {[La2(β-ala)6(H2O)4](ClO4)6 • H2O}n
    Ma, LF
    Liang, FP
    Qin, HC
    Zhang, MB
    Hu, R
    Yu, KB
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (02) : 205 - 208
  • [20] Thermal behavior of [Ca(H2O)4](ClO4)2 and [Ca(NH3)6](ClO4)2
    Anna Migdał-Mikuli
    Joanna Hetmańczyk
    Journal of Thermal Analysis and Calorimetry, 2008, 91 : 529 - 534
12345