Accurate quartic and sextic centrifugal distortion constants of CH3CP

被引:7
|
作者
Bizzocchi, L [1 ]
Cludi, L [1 ]
Degli Esposti, C [1 ]
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
关键词
D O I
10.1016/S0022-2852(02)00080-2
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
1-Phosphapropyne has been produced in the gas phase by pyrolysis of a mixture of ethane and phosphorus trichloride. The ground state rotational spectra of the most abundant isotopomer and of the isotopic variants (CH3CP)-C-13 and (CH3CP)-C-13 have been investigated in the millimeter and submillimeter wave regions obtaining very accurate values of the quartic centrifugal distortion constants D-J and D-JK and of the sextic distortion constants H-JK and H-KJ. (C) 2003 Elsevier Science (USA). All rights reserved.
引用
收藏
页码:53 / 57
页数:5
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