Study of Dielectric and Acoustic Properties of Binary Liquid Mixtures of Cyclohexane with n-Butanol at 308 K

被引:2
|
作者
Maharolkar, Aruna P. [1 ]
Murugkar, A. G. [2 ]
Khirade, P. W. [2 ]
Mehrota, S. C. [3 ]
机构
[1] Mandals Marathwada Inst Technol, Aurangabad 431004, Maharashtra, India
[2] Dr BAM Univ, Dept Phys, Aurangabad 431004, Maharashtra, India
[3] Dr BAM Univ, Dept Comp Sci & Informat Technol, Aurangabad 431004, Maharashtra, India
关键词
Bruggeman factor; compressibility; excess Gibbs free energy; enthalpy; excess inverse relaxation time; REFRACTIVE-INDEX; ALCOHOLS; VISCOSITY; AMINES; IR; COMBUSTION; SIMULATION; DEPENDENCE; 2-BUTANOL; EMISSIONS;
D O I
10.1134/S0036024421140120
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Present paper deals with study of dielectric constant, density and ultrasonic velocity and derived properties for the binary mixtures of cyclohexane and n-butanol over the entire concentration range measured at 308 K. The experimental data were further used to calculate derived parameters like Bruggeman factor, Gibbs free energy, enthalpy of activation, compressibility, and acoustic impedance, molecular free length, inverse relaxation time and excess parameters. The values of excess properties were further fitted with Redlich-Kister polynomial equation to estimate the binary coefficients and standard deviation. The resulting excess functions were interpreted in terms of the interactions between the molecules in the binary mixtures. Results confirm that weak bonded intermolecular interaction takes place between cyclohexane and n-butanol.
引用
收藏
页码:S56 / S61
页数:6
相关论文
共 50 条
  • [21] Thermodynamic properties of the binary mixture of water and n-butanol
    Nan, Z.
    Tan, Z-C.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 87 (02) : 539 - 544
  • [22] Densities and Viscosities of Binary Mixtures of n-Butanol with 2-Butanol, Isobutanol, and tert-Butanol from (303.15 to 343.15) K
    Bravo-Sanchez, Micael G.
    Iglesias-Silva, Gustavo A.
    Estrada-Baltazar, Alejandro
    Hall, Kenneth R.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (06): : 2310 - 2315
  • [23] Densities and surface tensions of binary mixtures of biodiesel, diesel, and n-butanol
    Hongya Yue
    Zhigang Liu
    Korean Journal of Chemical Engineering, 2016, 33 : 1692 - 1697
  • [24] Densities and surface tensions of binary mixtures of biodiesel, diesel, and n-butanol
    Yue, Hongya
    Liu, Zhigang
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (05) : 1692 - 1697
  • [25] Study on solid-liquid phase equilibria and excess Gibbs free energies for binary mixtures of n-butanol and xylene
    Che, Guanquan
    Yang, Yangyi
    Yun, Fengcun
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 14 (01): : 73 - 76
  • [26] Thermophysical properties of N,N-dimDμthylacetamide mixtures with n-butanol
    Maharolkar, Aruna P.
    Murugkar, A. G.
    Khirade, P. W.
    Mehrotra, S. C.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (09) : 1710 - 1716
  • [27] Thermophysical properties of N,N-dimеthylacetamide mixtures with n-butanol
    Aruna P. Maharolkar
    A. G. Murugkar
    P. W. Khirade
    S. C. Mehrotra
    Russian Journal of Physical Chemistry A, 2017, 91 : 1710 - 1716
  • [28] Acoustic and thermodynamic properties of a binary liquid cyclohexane + n-hexadecane mixture
    T. S. Khasanshin
    N. V. Golubeva
    V. S. Samuilov
    A. P. Shchemelev
    High Temperature, 2017, 55 : 685 - 692
  • [29] Vapour-liquid equilibrium study of binary mixtures of aniline with isopropanol, n-butanol and ethylene glycol at the local atmospheric pressure
    Mali, Pawan K.
    Mali, Nilesh A.
    Yadav, Satyajeet S.
    Joshi, Sunil S.
    INDIAN CHEMICAL ENGINEER, 2019, 61 (02) : 195 - 205
  • [30] Molecular interaction studies in binary mixtures containing aniline, toluene and n-butanol
    Lakshmanan, Palaniappan
    Govindasamy, Mahendran
    TURKISH JOURNAL OF PHYSICS, 2011, 35 (03): : 303 - 310