Liberation of alkali salts from fluxed iron ore pellets during induration

During the induration of fluxed taconite pellets, alkali salts deposit on the grate support bars, causing severe corrosive degradation of these alloys. To determine the source of these deposits and to understand the mechanism by which the salts are conveyed to the grate bars, a study of the reactions between fluxed pellets and combustion gas was carried out. The study focused on the thermodynamics and kinetics of several processes associated with induration; namely, oxidation of magnetite, calcination of flux, and the formation and gaseous transport of various alkali salt species. Both theoretical and experimental techniques were used. It was concluded that the principal source of alkali salt deposits is alkali chlorides, which are present as contaminants in the flux and/or residue from contaminated washwater. The pathway from pellet to grate bar involves the following steps: evaporation of chloride salts within the pellet; diffusion of salt vapor out of the pellet, aided by the outflow of CO2 from calcination of the flux, convective transport by the combustion gas with concurrent (partial) conversion to alkali sulfates by reaction with residual SOx in the combustion gas; and condensation of salts on the grate bars.