New syntheses and crystal structures of bis(fluorophenyl) mercury, Hg(Rf)2 (Rf = C6F5, 2,3,4,6-F4C6H, 2,3,5,6-F4C6H, 2,4,6-F3C6H2, 2,6-F2C6H3)

被引：6
|
作者：
Naumann, D [1 ]
Schulz, F [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 01期
关键词：
mercury; fluorophenyl compounds; crystal structures;
D O I：
10.1002/zaac.200400244
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Bis(fluorophenyl) mercury compounds, Hg(R-f)(2) (R-f = C6F5, C6HF4, C6H2F3, C6H3F2), are prepared in good yields by the reactions of HgF2 with Me3SiRf. The crystal structures of Hg(2,3,4,6-F4C6H)(2) (monoclinic, P2(1)/n), Hg(2,3,5,6-F4C6H)(2) (monoclinic, C2/m), Hg(2,4,6-F3C6H2)(2) (monoclinic, P2(1)/c) and Hg(2,6-F2C6H3)(2) (triclinic, P (1) over bar) are described.
引用
下载
收藏
页码：122 / 125
页数：4
相关论文
共 50 条
  • [1] Investigations on syntheses and reactions of fluorophenylmercury compounds with the ligands 2-FC6H4, 2,6-F2C6H3, and 2,4,6-F3C6H2
    Layeghi, H
    Tyrra, W
    Naumann, D
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (10): : 1601 - 1610
  • [2] ELECTRONICALLY EXCITED-STATES OF [C6H5F]2+, [C6H5CL]2+, [2-CL-C6H4F]2+, [3-CL-C6H4F]2+ AND [4-CL-C6H4F]2+
    LANGFORD, ML
    HARRIS, FM
    ORGANIC MASS SPECTROMETRY, 1991, 26 (10): : 917 - 919
  • [3] Synthesis and Structures of Tetraphenylantimony Aroxides Ph4SbOAr (Ar = C6H3F2-2,4, C6H3F2-2,5, C6H3Cl-2-F-4)
    Sharutin, V. V.
    Sharutina, O. K.
    Efremov, A. N.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2021, 47 (06) : 393 - 398
  • [4] Synthesis and Structures of Tetraphenylantimony Aroxides Ph4SbOAr (Ar = C6H3F2-2,4, C6H3F2-2,5, C6H3Cl-2-F-4)
    V. V. Sharutin
    O. K. Sharutina
    A. N. Efremov
    Russian Journal of Coordination Chemistry, 2021, 47 : 393 - 398
  • [5] Synthesis and Structures of Tris(3-fluorophenyl)antimony Dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, and C6F5)
    Sharutin, V. V.
    Sharutina, O. K.
    Zherebtsov, D. A.
    El'tsov, O. S.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (04) : 218 - 223
  • [6] Palladium(II) compounds with fluorinated pincer-type (SCS) ligands:: X-ray structures of C6H4-1,3-(CH2SC6H4F-4)2 and [PdCl(SCS-Rf)] [Rf = C6H4F-2, C6H4F-3, C6H4F-4, C6H4(CF3)-2, and C6H4(CF3)-4]
    Cervantes, R
    Castillejos, S
    Loeb, SJ
    Ortiz-Frade, L
    Tiburcio, J
    Torrens, H
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (05) : 1076 - 1083
  • [7] THIOLATE COMPLEXES OF OSMIUM(IV) - PREPARATION OF [OS(SR)4(PR'3)] (R = C6F5, C6F4H-4, C6H4F-4 OR PH, R' = PH R = C6F5 OR C6F4H-4, R'3 = ME2PH) AND [OSCL(SC6F5)2(SC6H4X-3)(PME2PH)] (X=F OR CF3) - CRYSTAL-STRUCTURES OF [OS(SC6F4H-4)4(PPH3)] AND [OSCL(SC6F5)2(SC6H4CF3-3)(PME2PH)]
    ARROYO, M
    CHAMIZO, JA
    HUGHES, DL
    RICHARDS, RL
    ROMAN, P
    SOSA, P
    TORRENS, H
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (13): : 1819 - 1824
  • [8] Equilibria in the B(C6F5)3-H2O system:: synthesis and crystal structures of H2O•B(C6F5)3 and the anions [HOB(C6F5)3]- and [F5C6)3B(μ-OH)B(C6F5)3]-
    Danopoulos, AA
    Galsworthy, JR
    Green, MLH
    Cafferkey, S
    Doerrer, LH
    Hursthouse, MB
    CHEMICAL COMMUNICATIONS, 1998, (22) : 2529 - 2530
  • [9] ASIS EFFECTS ON H-1 AND F-19 NUCLEI OF DIPOLAR SOLUTES IN C6F6, C6H5F, PARA C6H4F2, 1,2,4,5-C6H2F4 AND C6H6
    MOSBO, J
    VERKADE, JG
    JOURNAL OF MAGNETIC RESONANCE, 1972, 8 (03) : 250 - &
  • [10] SOME REACTIONS OF OXYGEN ATOMS .1. C2F4 C3F6 C2H2 C2H4 C3H6 1-C4H8 C2H6 C-C3H6 AND C3H8
    SAUNDERS, D
    HEICKLEN, J
    JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (06): : 1950 - &
12345