The selective functionalization of saturated hydrocarbons. Part 43. Modified Gif oxidation in acetonitrile

被引：21
|
作者：
Barton, DHR [1 ]
Li, TS [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
来源：
TETRAHEDRON | 1998年 / 54卷 / 09期
关键词：
D O I：
10.1016/S0040-4020(97)10398-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The role of pyridine and of many substituted pyridines in Gif oxidation chemistry has been examined. In the presence of a suitable pyridine type base most of the solvent can be replaced by acetonitrile without diminishing the yield of oxidation products. The use of 4-tert-butylpyridine permits the isolation of cyclohexanone and cyclohexanol by simple distillation. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码：1735 / 1744
页数：10
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