Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex

被引：57
|
作者：
Harvey, Peter [1 ]
Nonat, Aline [2 ]
Platas-Iglesias, Carlos [3 ,4 ]
Natrajan, Louise S. [1 ]
Charbonniere, Loic J. [2 ]
机构：
[1] Univ Manchester, Ctr Radiochem Res, Sch Chem, Brunswick St, Manchester M13 9PL, Lancs, England
[2] ECPM, Lab Ingn Mol Appl & Anal, IPHC, UMR 7178, 25 Rue Becquerel, F-67087 Strasbourg 02, France
[3] Univ A Coruna, CICA, Campus Zapateira Rua Fraga 10, La Coruna 15008, Spain
[4] Univ A Coruna, Dept Quim, Campus Zapateira Rua Fraga 10, La Coruna 15008, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 31期
基金：
英国工程与自然科学研究理事会;
关键词：
energy transfer; europium; luminescence; sensors; uranyl; MULTIWAVELENGTH SPECTROSCOPIC DATA; MRI CONTRAST AGENTS; EQUILIBRIUM-CONSTANTS; URANIUM(VI); SYSTEMS; UO22+; EU3+; METAL;
D O I：
10.1002/anie.201805316
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The release of uranyl(VI) is a hazardous environmental issue, with limited ways to monitor accumulation in situ. Here, we present a method for the detection of uranyl(VI) ions through the utilization of a unique fluorescence energy transfer process to europium(III). Our system displays the first example of a turn-on europium(III) emission process with a small, water-soluble lanthanide complex triggered by uranyl(VI) ions.
引用
收藏
页码：9921 / 9924
页数：4
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