Sensing Uranyl(VI) Ions by Coordination and Energy Transfer to a Luminescent Europium(III) Complex

被引:57
|
作者
Harvey, Peter [1 ]
Nonat, Aline [2 ]
Platas-Iglesias, Carlos [3 ,4 ]
Natrajan, Louise S. [1 ]
Charbonniere, Loic J. [2 ]
机构
[1] Univ Manchester, Ctr Radiochem Res, Sch Chem, Brunswick St, Manchester M13 9PL, Lancs, England
[2] ECPM, Lab Ingn Mol Appl & Anal, IPHC, UMR 7178, 25 Rue Becquerel, F-67087 Strasbourg 02, France
[3] Univ A Coruna, CICA, Campus Zapateira Rua Fraga 10, La Coruna 15008, Spain
[4] Univ A Coruna, Dept Quim, Campus Zapateira Rua Fraga 10, La Coruna 15008, Spain
基金
英国工程与自然科学研究理事会;
关键词
energy transfer; europium; luminescence; sensors; uranyl; MULTIWAVELENGTH SPECTROSCOPIC DATA; MRI CONTRAST AGENTS; EQUILIBRIUM-CONSTANTS; URANIUM(VI); SYSTEMS; UO22+; EU3+; METAL;
D O I
10.1002/anie.201805316
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The release of uranyl(VI) is a hazardous environmental issue, with limited ways to monitor accumulation in situ. Here, we present a method for the detection of uranyl(VI) ions through the utilization of a unique fluorescence energy transfer process to europium(III). Our system displays the first example of a turn-on europium(III) emission process with a small, water-soluble lanthanide complex triggered by uranyl(VI) ions.
引用
收藏
页码:9921 / 9924
页数:4
相关论文
共 50 条
  • [1] ENERGY-TRANSFER BETWEEN URANYL(VI) AND EUROPIUM(III) IN AQUEOUS PERCHLORATE SOLUTION
    TANNER, SP
    VARGENAS, AR
    INORGANIC CHEMISTRY, 1981, 20 (12) : 4384 - 4386
  • [2] LARGE ENERGY TRANSFER FROM URANYL TO EUROPIUM IONS IN GLASS
    DESHAZER, LG
    CABEZAS, AY
    PROCEEDINGS OF THE IEEE, 1964, 52 (11) : 1355 - &
  • [3] Highly specific "sensing" of tryptophan by a luminescent europium(III) complex
    Stubenrauch, Jan A.
    Mevissen, Christian
    Schulte, Marie F.
    Bochenek, Steffen
    Albrecht, Markus
    Subramanian, Palani S.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2016, 71 (10): : 1025 - 1028
  • [4] Sensing of biologically relevant anions with a luminescent europium(III) complex
    Felix, Kayla
    Johnson, Katherine
    Werner, Eric
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [5] CORRECTION TO LARGE ENERGY TRANSFER FROM URANYL TO EUROPIUM IONS IN GLASS
    DESHAZER, LG
    CABEZAS, AY
    PROCEEDINGS OF THE INSTITUTE OF ELECTRICAL AND ELECTRONICS ENGINEERS, 1965, 53 (03): : 305 - &
  • [6] Preparation of a Molecularly Imprinted Polymer Containing Europium(III) Ions for Luminescent Sensing
    Kim, Hyungwoo
    Kim, Youngdo
    Chang, Ji Young
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (23) : 4990 - 4994
  • [7] Luminescent europium(III) complexes for anion sensing
    Benjamin, Tavya G. R.
    Werner, Eric J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [8] Ab Initio Study of Energy Transfer Pathways in Dinuclear Lanthanide Complex of Europium(III). and Terbium(III) Ions
    Romanova, Ksenia A.
    Freidzon, Alexandra Ya.
    Bagaturyants, Alexander A.
    Galyametdinov, Yury G.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (47): : 11244 - 11252
  • [9] An ionic luminescent complex of europium(III) and its fluorescence sensing performance for amine VOCs
    Dai, Ding-Qiu
    Song, Li
    Wu, Jin-Tao
    Jin, Ding-Fen
    Jin, Hong-Xiao
    Shen, Hang-Yan
    Du, Xin-Yang
    Zhang, Ying-Ying
    Chai, Wen-Xiang
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1319
  • [10] Synthesis, Structure and Luminescent Property of an Europium(III) Coordination Polymer
    Ye Yan-Zhu
    Lin Shen
    Wu Xin-Jian
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (11) : 1649 - 1654