Crystal structure and Hirshfeld surface analysis of 5,7-diphenyl-1,2,3,5,6,7-hexahydroimidazo[1,2-a]-pyridine-6,6,8-tricarbonitrile methanol monosolvate

被引：0

作者：

Naghiyev, Farid N. ^{[1
]}

Mammadova, Gunay Z. ^{[1
]}

Khalilov, Ali N. ^{[1
,2
]}

Atioglu, Zeliha ^{[3
]}

Akkurt, Mehmet ^{[4
]}

Akobirshoeva, Anzurat A. ^{[5
]}

Mamedov, Ibrahim G. ^{[1
]}

机构：

[1] Baku State Univ, Dept Chem, Z Khalilov Str 23, AZ-1148 Baku, Azerbaijan

[2] Azerbaijan State Econ Univ UNEC, Composite Mat Sci Res Ctr, H Aliyev Str 135, AZ-1063 Baku, Azerbaijan

[3] Cappadocia Univ, Sch Appl Sci, Dept Aircraft Elect & Elect, TR-50420 Urgup, Nevsehir, Turkey

[4] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey

[5] Acad Sci Republ Tadzhikistan, Kh Yu Yusufbekov Pamir Biol Inst, 1 Kholdorova St, Khorog 736002, Gbao, Tajikistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷

关键词：

crystal structure; imidazolidine ring; pyridine ring; hydrogen bond; Hirshfeld surface analysis;

D O I：

10.1107/S2056989021004655

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C22H17N5 center dot CH4O, the imidazolidine ring of the 1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyridine ring system is a twisted envelope, while the 1,2,3,4-tetrahydropyridine ring adopts a twisted boat conformation. In the crystal, pairs of molecules are linked by O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds via two methanol molecules, forming a centrosymmetric R-4(4)(16) ring motif. These motifs are connected to each other by C-H center dot center dot center dot N hydrogen bonds and form columns along the a axis. The columns form a stable molecular packing, being connected to each other by van der Waals interactions. A Hirshfeld surface analysis indicates that the most significant contributions to the crystal packing are from H center dot center dot center dot H (43.8%), N center dot center dot center dot H/H center dot center dot center dot N (31.7%) and C center dot center dot center dot H/H center dot center dot center dot C (18.4%) contacts.

引用

页码：600 / +

页数：11

共 50 条

[21] A FACILE SYNTHESIS OF 5,7-DIHYDRO-5-OXOPYRIDO[3',2'-5,6]PYRIMIDO[1,2-A]BENZIMIDAZOLES - A NEW HETEROCYCLIC RING-SYSTEM
CAROTI, P
CECCOTTI, C
DASETTIMO, A
PALLA, F
PRIMOFIORE, G
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1986, 23 (06) : 1833 - 1836
[22] Crystal structure and Hirshfeld surface analysis of 5-(5-phenyl-1,2-oxazol-3-yl)-1,3,4-thiadiazol-2-amine
Nikitina, Evgeniya, V
Celikesir, Sevim Turktekin
Akkurt, Mehmet
Petkevich, Sergey K.
Akishina, Ekaterina A.
Khrustalev, Victor N.
Mlowe, Sixberth
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 453 - +
[23] Crystal structure and Hirshfeld surface analysis of bis[hydrazinium(1+)] hexafluoridosilicate: (N2H5)2SiF6
Ouasri, Ali
Lambarki, Fatima
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1507 - +
[24] 2,2,5,5,8,8-Hexamethyl-2,3,5,6,7,8-hexahydroimidazo[1,2-a]pyrazine-3,6-dione, a bicyclic product of α-aminoisobutyric acid condensation
Basiuk, VA
Van Meervelt, L
Soloshonok, VA
Basiuk, EV
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : 598 - 599
[25] An approach to novel fused triazole or tetrazole derivatives starting from benzimidazo[1,2-a]quinazoline-5(7H)-one and 5,7-dihydro-5-oxopyrido[3′,2′:5,6]pyrimido[1,2-a]benzimidazole
Da Settimo, A
Primofiore, G
Da Settimo, F
Pardi, G
Simorini, F
Marini, AM
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2002, 39 (05) : 1007 - 1011
[26] Crystal structure and Hirshfeld surface analysis of two imidazo[1,2-a]pyridine derivatives: N-tert-butyl-2-(4-methoxyphenyl)-5-methylimidazo-[1,2-a]pyridin-3-amine and N-tert-butyl-2-[4-(di-methylamino)phenyl]imidazo[1,2-a]pyridin-3-amine
Dhanalakshmi, G.
Ramanjaneyulu, Mala
Thennarasu, Sathiah
Aravindhan, S.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1913 - +
[27] 5-Amino-6-benzoyl-8-nitro-2,3-dihydro-1H-spiro[imidazo[1,2-a] pyridine-7,3 '-indolin]-2 '-one dimethyl sulfoxide monosolvate
Nagalakshmi, R. A.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O604 - +
[28] Crystal structure and Hirshfeld surface analysis of 6-amino-8-phenyl-1,3,4,8-tetrahydro-2H-pyrido-[1,2-a]pyrimidine-7,9-dicarbonitrile
Naghiyev, Farid N.
Tereshina, Tatiana A.
Khrustalev, Victor N.
Akkurt, Mehmet
Khalilov, Ali N.
Akobirshoeva, Anzurat A.
Mamedov, Ibrahim G.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 512 - +
[29] Crystal structure characterization, Hirshfeld surface analysis, and DFT calculation studies of 1-(6-amino-5-nitronaphthalen-2-yl)ethanone
Shi, Xin-Wei
Bai, Ming-Sheng
Zheng, Shao-Jun
Lu, Qiang-Qiang
Li, Gen
Zhou, Ya-Fu
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 561 - +
[30] Crystal structure, DFT study, and Hirshfeld surface analysis of ethyl 5-(3,4-dimethoxyphenyl)-7-methyl-3-phenyl-5H-thiazolo[ 3,2-A]pyrimidine-6-carboxylate
Shelke, A.
Karade, N. N.
Dutta, P. Kr.
Bahekar, S. P.
Chandak, H. S.
JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (07) : 1246 - 1252

← 1 2 3 4 5 →