P(RNCH2CH2)3N:: Very strong non-ionic bases useful in organic synthesis

被引：0
|
作者：
Verkade, JG [1 ]
机构：
[1] Iowa State Univ, Dept Chem, Ames, IA 50010 USA
来源：
NEW ASPECTS IN PHOSPHORUS CHEMISTRY II | 2003年 / 223卷
关键词：
pro-azaphosphatranes; transannulation; catalysis; basicity; nitrogen bases;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bases of the title type (pro-azaphosphatranes) are very strong (pK(a) ca. 32 in acetonitrile). After briefly reviewing recent uses of popular nitrogen-containing bases of various types, the synthesis, unusual structural features and unique chemical characteristics of pro-azaphosphatranes and some of their derivatives are described. Recent advances in utilizing pro-azaphosphatranes as stoichiometric reagents and as catalysts in a wide variety of useful organic transformations are then summarized. In their role as catalysts, pro-azaphosphatranes are seen not only to act as deprotonation agents, but also to activate for further reaction of carbon and silicon in several substrates possessing such atoms.
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页码：1 / 44
页数：44
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