P(RNCH2CH2)3n as very strong non-ionic bases and catalysts:: Recent advances and applications

被引：12
|
作者：
Verkade, JG [1 ]
机构：
[1] Iowa State Univ, Dept Chem, Ames, IA 50010 USA
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2002年 / 177卷 / 6-7期
关键词：
bases; carbon-fluorine activation; catalysts; proazaphosphatranes; transannulation;
D O I：
10.1080/10426500212298
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A rationale for the unusually strong Lewis basicity and catalytic activity of the title pro-azaphosphatranes is presented. Four stoichiometric and four catalytic uses of such pro-azaphosphatranes are described, as well as some unexpected reactions in which these bases take part. Mechanistic pathways are put forth for several of the transformations outlined.
引用
收藏
页码：1621 / 1631
页数：11
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