A new zirconocene complex, [{eta(5)-C5H4-C(CH2)(5)(CH2)(2)CH(CH3)(2)}2ZrCl2]

被引：1

作者：

Tian, J

Li, H

Hu, NH

Huang, BT

机构：

[1] Changchun Inst. of Applied Chemistry, Chinese Academy of Sciences

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195005543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, dichlorobis{eta(5)-[1-(3-methylbutyl)-cyclohex-1 -yl]cyclopentadienyl}zirconium(IV), [ZrCl2-(C16H25)(2)], has a pseudo-tetrahedral bent-metallocene structure in which the substituted cyclopentadienyl rings are asymmetrically bonded to the central Zr atom, due primarily to the interaction between the large substituents and the Cl atoms. The molecule has local C-2 symmetry with the substituents positioned in a trans arrangement and directed towards the lateral sectors of the bent-metallocene unit.

引用

页码：19 / 21

页数：3

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