Direct oxidative esterification of toluene with 1,3-dicarbonyl compounds catalysed by copper complex supported on magnetic nanoparticles

被引：11

作者：

Azizi, Kobra ^{[1
]}

Esfandiary, Naghmeh ^{[1
]}

Karimi, Meghdad ^{[1
]}

Kazemi, Maryam ^{[1
]}

Heydari, Akbar ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Chem Dept, POB 14155-4838, Tehran, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 08期

关键词：

esterification; magnetic; nanoparticles; oxidation; toluene; LIQUID-PHASE OXIDATION; CARBOXYLIC-ACIDS; ALDEHYDES; ALCOHOLS; AMIDATION;

D O I：

10.1002/aoc.3658

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Toluene oxidation is one of the substantial industrial technologies since oxidized products are industrially very important intermediates. A Fe3O4@cysteine@Cu-catalysed reaction that uses tert-butyl hydroperoxide as oxidant to produce esters from toluene and beta-diketones or beta-keto esters, enolate precursors, has been developed. Oxidative esterification of toluene with 1,3-dicarbonyl derivatives led to C-O bond formation and direct C-H functionalization.

引用

页数：7

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