Direct oxidative esterification of toluene with 1,3-dicarbonyl compounds catalysed by copper complex supported on magnetic nanoparticles

被引：11
|
作者：
Azizi, Kobra [1 ]
Esfandiary, Naghmeh [1 ]
Karimi, Meghdad [1 ]
Kazemi, Maryam [1 ]
Heydari, Akbar [1 ]
机构：
[1] Tarbiat Modares Univ, Chem Dept, POB 14155-4838, Tehran, Iran
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 08期
关键词：
esterification; magnetic; nanoparticles; oxidation; toluene; LIQUID-PHASE OXIDATION; CARBOXYLIC-ACIDS; ALDEHYDES; ALCOHOLS; AMIDATION;
D O I：
10.1002/aoc.3658
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Toluene oxidation is one of the substantial industrial technologies since oxidized products are industrially very important intermediates. A Fe3O4@cysteine@Cu-catalysed reaction that uses tert-butyl hydroperoxide as oxidant to produce esters from toluene and beta-diketones or beta-keto esters, enolate precursors, has been developed. Oxidative esterification of toluene with 1,3-dicarbonyl derivatives led to C-O bond formation and direct C-H functionalization.
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页数：7
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