A convenient synthesis of fluoroalkyl ketones and sulfones from perfluoroisopropyl iodide

被引：2
|
作者：
Chen, JG [1 ]
Kirchmeier, RL [1 ]
Shreeve, JM [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 89卷 / 01期
关键词：
diglyme; perfluoroisopropyl iodide; benzonitrile;
D O I：
10.1016/S0022-1139(98)00078-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the presence of hexaethylphosphorus triamide (HEPT), perfuoroisopropyl iodide is reacted directly with perfluoroalkyl acid halides, trifluoromethanesulfonyl fluoride, and methanesulfonyl chloride ir benzonitrile to give the corresponding fluorinated ketones and sulfones. Diglyme is the solvent of choice for the reaction of pentafluorobenzoyl chloride with perfluoroisopropyl iodide in the presence of HEPT. (C) 1998 Elsevier Science S.A.
引用
收藏
页码：5 / 8
页数：4
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