Preparation of triarylantimony(V) diacetates and palladium-catalyzed cross-coupling and carbonylative cross-coupling of triarylantimony(V) diacetates and dichlorides with organostannanes

被引:33
|
作者
Kang, SK
Ryu, HC
Lee, SW
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Inst Basic Sci, Suwon 440746, South Korea
基金
新加坡国家研究基金会;
关键词
organoantimony compounds; palladium-catalyzed; cross-coupling; carbonylative; organostannanes;
D O I
10.1016/S0022-328X(00)00386-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Triarylstibines react with iodobenzene diacetate in dichloromethane to afford triarylantimony(V) diacetates. The cross-coupling and carbonylative cross-coupling of triarylantimony(V) diacetates and dichlorides with organostannanes was accomplished in the presence of PdCl2 (5 mol%) in CH3CN at room temperature. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
引用
收藏
页码:38 / 41
页数:4
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