Room-Temperature Copper-Catalyzed Synthesis of Primary Arylamines from Aryl Halides and Aqueous Ammonia

被引：20

作者：

Tao, Chuanzhou ^{[1
]}

Liu, Weiwei ^{[1
]}

Lv, Aifeng ^{[2
]}

Sun, Mingming ^{[1
]}

Tian, Ying ^{[1
]}

Wang, Qi ^{[1
]}

Zhao, Jing ^{[2
]}

机构：

[1] Huaihai Inst Technol, Sch Chem Engn, Lianyungang, Peoples R China

[2] Nanjing Univ, Sch Life Sci, State Key Lab Pharmaceut Biotechnol, Nanjing 210093, Peoples R China

来源：

SYNLETT | 2010年 / 09期

关键词：

copper; catalysis; cross-coupling; room temperature; aqueous ammonia; primary arylamine; BOND FORMATION; N-ARYLATION; NITROGEN LIGANDS; C-N; AMINATION; BROMIDES; ANILINES; AMINES; EQUIVALENTS; AMIDATION;

D O I：

10.1055/s-0029-1219922

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Primary arylamines can be prepared via a copper-catalyzed cross-coupling between aryl halides and aqueous ammonia using K3PO4 as a base and DMF as a solvent at room temperature.

引用

页码：1355 / 1358

页数：4

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