Synthesis of new 1,3-bis(Heteroaryl)-4,5-imidazolidinediones through reaction of N,N′-bis(Heteroaryl)methanediamines with oxalyl chloride

被引：1

作者：

Ghandi, Mehdi ^{[1
]}

Salimi, Farshid ^{[1
]}

机构：

[1] Univ Tehran, Univ Coll Sci, Sch Chem, Tehran, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2007年 / 37卷 / 4-6期

关键词：

4,5-imidazolidinediones; methanediamine; oxalyl chloride;

D O I：

10.1080/00397910601055248

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of N,N'-bis(2-pyridinyl, 3-pyridinyl, 4-pyridinyl, 2-thiazolyl, 4-nitrophenyl, and 2-benzothiazolyl)methanediamines 1a-f with oxalyl chloride in dry dichloroethane in the presence of pyridine affords the corresponding 1,3-bis (heteroaryt)-4,5-imidazolidinediones 3a-f in good to excellent yields. The essential role of pyridine in the reaction mixture is described, and reaction details as well as product characterization is discussed.

引用

页码：637 / 644

页数：8

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